Carbonization of coals to produce anisotropic cokes. 4. Improving co-carbonization behaviour of bituminous and subbituminous coals with pitch by pretreatment coals to remove cations

Isao Mochida, Takaaki Shimohara, Yozo Korai, Hiroshi Fujitsu, Kenjiro Takeshita

Research output: Contribution to journalArticle

13 Citations (Scopus)

Abstract

Several de-ashing pretreatments of selected coals have been examined to establish simple and effective procedures to improve, in terms of anisotropic development, the co-carbonization behaviour of the coals with pitches. Refluxing pretreatments of the coals in 1N HCI containing methanol and in boiling water containing EDTA-2Na (EDTA-2Na/coal = 7/100 by weight) improve the co-carbonization behaviour of Witbank, Miller, Taiheiyo and Wandoan coals, all of which, in their original, untreated form, are modified in terms of anisotropic development only very slightly in co-carbonizations with A240 petroleum pitch. Pretreatment of coals of very low rank appears to be ineffective in co-carbonizations with A240; however, co-carbonization with hydrogenated A240 shows that the pretreatments are effective. Analyses and FT-i.r. spectroscopy of mineral matter suggest that improved behaviour due to the pretreatment is related to the removal of divalent cations and to the modification of the oxygen functionality of the coals.

Original languageEnglish
Pages (from-to)659-664
Number of pages6
JournalFuel
Volume62
Issue number6
DOIs
Publication statusPublished - Jan 1 1983

Fingerprint

Coal
Carbonization
Cations
Positive ions
Ethylenediaminetetraacetic acid
Edetic Acid
Divalent Cations
Petroleum
Human computer interaction
Boiling liquids
Minerals
Methanol
Crude oil
Spectroscopy
Oxygen
Water

All Science Journal Classification (ASJC) codes

  • Chemical Engineering(all)
  • Fuel Technology
  • Energy Engineering and Power Technology
  • Organic Chemistry

Cite this

Carbonization of coals to produce anisotropic cokes. 4. Improving co-carbonization behaviour of bituminous and subbituminous coals with pitch by pretreatment coals to remove cations. / Mochida, Isao; Shimohara, Takaaki; Korai, Yozo; Fujitsu, Hiroshi; Takeshita, Kenjiro.

In: Fuel, Vol. 62, No. 6, 01.01.1983, p. 659-664.

Research output: Contribution to journalArticle

Mochida, Isao ; Shimohara, Takaaki ; Korai, Yozo ; Fujitsu, Hiroshi ; Takeshita, Kenjiro. / Carbonization of coals to produce anisotropic cokes. 4. Improving co-carbonization behaviour of bituminous and subbituminous coals with pitch by pretreatment coals to remove cations. In: Fuel. 1983 ; Vol. 62, No. 6. pp. 659-664.
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abstract = "Several de-ashing pretreatments of selected coals have been examined to establish simple and effective procedures to improve, in terms of anisotropic development, the co-carbonization behaviour of the coals with pitches. Refluxing pretreatments of the coals in 1N HCI containing methanol and in boiling water containing EDTA-2Na (EDTA-2Na/coal = 7/100 by weight) improve the co-carbonization behaviour of Witbank, Miller, Taiheiyo and Wandoan coals, all of which, in their original, untreated form, are modified in terms of anisotropic development only very slightly in co-carbonizations with A240 petroleum pitch. Pretreatment of coals of very low rank appears to be ineffective in co-carbonizations with A240; however, co-carbonization with hydrogenated A240 shows that the pretreatments are effective. Analyses and FT-i.r. spectroscopy of mineral matter suggest that improved behaviour due to the pretreatment is related to the removal of divalent cations and to the modification of the oxygen functionality of the coals.",
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AU - Takeshita, Kenjiro

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N2 - Several de-ashing pretreatments of selected coals have been examined to establish simple and effective procedures to improve, in terms of anisotropic development, the co-carbonization behaviour of the coals with pitches. Refluxing pretreatments of the coals in 1N HCI containing methanol and in boiling water containing EDTA-2Na (EDTA-2Na/coal = 7/100 by weight) improve the co-carbonization behaviour of Witbank, Miller, Taiheiyo and Wandoan coals, all of which, in their original, untreated form, are modified in terms of anisotropic development only very slightly in co-carbonizations with A240 petroleum pitch. Pretreatment of coals of very low rank appears to be ineffective in co-carbonizations with A240; however, co-carbonization with hydrogenated A240 shows that the pretreatments are effective. Analyses and FT-i.r. spectroscopy of mineral matter suggest that improved behaviour due to the pretreatment is related to the removal of divalent cations and to the modification of the oxygen functionality of the coals.

AB - Several de-ashing pretreatments of selected coals have been examined to establish simple and effective procedures to improve, in terms of anisotropic development, the co-carbonization behaviour of the coals with pitches. Refluxing pretreatments of the coals in 1N HCI containing methanol and in boiling water containing EDTA-2Na (EDTA-2Na/coal = 7/100 by weight) improve the co-carbonization behaviour of Witbank, Miller, Taiheiyo and Wandoan coals, all of which, in their original, untreated form, are modified in terms of anisotropic development only very slightly in co-carbonizations with A240 petroleum pitch. Pretreatment of coals of very low rank appears to be ineffective in co-carbonizations with A240; however, co-carbonization with hydrogenated A240 shows that the pretreatments are effective. Analyses and FT-i.r. spectroscopy of mineral matter suggest that improved behaviour due to the pretreatment is related to the removal of divalent cations and to the modification of the oxygen functionality of the coals.

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