Catalytic asymmetric epoxidation of unfunctionalized olefins

Ryo Irie; Keiko Noda; Yoshio Ito; Naohide Matsumoto; Tsutomu Katsuki

doi:10.1016/S0040-4039(00)88562-7

Catalytic asymmetric epoxidation of unfunctionalized olefins

Ryo Irie, Keiko Noda, Yoshio Ito, Naohide Matsumoto, Tsutomu Katsuki

Organic and Biological Chemistry

Research output: Contribution to journal › Article › peer-review

657 Citations (Scopus)

Abstract

Manganese complex of the optically active salen ligand [N,N'-bis[(S)-3-(1-phenylpropyl)salicylidene]-(1R,2R)-1,2-diphenylethylenediaminato] was found to be an effective catalyst for the enantioselective epoxidation of unfunctionalized olefins. The highest enantioselectivity of 50% ee was realized for (E)-1-phenyl-1-propene.

Original language	English
Pages (from-to)	7345-7348
Number of pages	4
Journal	Tetrahedron Letters
Volume	31
Issue number	50
DOIs	https://doi.org/10.1016/S0040-4039(00)88562-7
Publication status	Published - 1990

All Science Journal Classification (ASJC) codes

Biochemistry
Drug Discovery
Organic Chemistry

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10.1016/S0040-4039(00)88562-7

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title = "Catalytic asymmetric epoxidation of unfunctionalized olefins",

abstract = "Manganese complex of the optically active salen ligand [N,N'-bis[(S)-3-(1-phenylpropyl)salicylidene]-(1R,2R)-1,2-diphenylethylenediaminato] was found to be an effective catalyst for the enantioselective epoxidation of unfunctionalized olefins. The highest enantioselectivity of 50% ee was realized for (E)-1-phenyl-1-propene.",

author = "Ryo Irie and Keiko Noda and Yoshio Ito and Naohide Matsumoto and Tsutomu Katsuki",

note = "Funding Information: Financial support by the Grand-in-Aid for Scientific Research in Priority Areas (02231222) from the Ministry of Education, Science, and Culture, Japan, is greatly acknowledged. The authors are also grateful to Professor Hisashi Okawa for his helpful discussions.",

year = "1990",

doi = "10.1016/S0040-4039(00)88562-7",

language = "English",

volume = "31",

pages = "7345--7348",

journal = "Tetrahedron Letters",

issn = "0040-4039",

publisher = "Elsevier Limited",

number = "50",

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TY - JOUR

T1 - Catalytic asymmetric epoxidation of unfunctionalized olefins

AU - Irie, Ryo

AU - Noda, Keiko

AU - Ito, Yoshio

AU - Matsumoto, Naohide

AU - Katsuki, Tsutomu

N1 - Funding Information: Financial support by the Grand-in-Aid for Scientific Research in Priority Areas (02231222) from the Ministry of Education, Science, and Culture, Japan, is greatly acknowledged. The authors are also grateful to Professor Hisashi Okawa for his helpful discussions.

PY - 1990

Y1 - 1990

N2 - Manganese complex of the optically active salen ligand [N,N'-bis[(S)-3-(1-phenylpropyl)salicylidene]-(1R,2R)-1,2-diphenylethylenediaminato] was found to be an effective catalyst for the enantioselective epoxidation of unfunctionalized olefins. The highest enantioselectivity of 50% ee was realized for (E)-1-phenyl-1-propene.

AB - Manganese complex of the optically active salen ligand [N,N'-bis[(S)-3-(1-phenylpropyl)salicylidene]-(1R,2R)-1,2-diphenylethylenediaminato] was found to be an effective catalyst for the enantioselective epoxidation of unfunctionalized olefins. The highest enantioselectivity of 50% ee was realized for (E)-1-phenyl-1-propene.

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U2 - 10.1016/S0040-4039(00)88562-7

DO - 10.1016/S0040-4039(00)88562-7

M3 - Article

AN - SCOPUS:0025678430

VL - 31

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EP - 7348

JO - Tetrahedron Letters

JF - Tetrahedron Letters

SN - 0040-4039

IS - 50

ER -

Catalytic asymmetric epoxidation of unfunctionalized olefins

Abstract

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