Catalytic asymmetric hydrolysis

Asymmetric hydrolytic protonation of enol esters catalyzed by phase-transfer catalysts

Eiji Yamamoto, Ayano Nagai, Akiyuki Hamasaki, Makoto Tokunaga

Research output: Contribution to journalArticle

22 Citations (Scopus)

Abstract

Like an enzyme: Asymmetric hydrolysis of enol esters is accomplished by chiral phase-transfer catalysts under biphasic base hydrolysis conditions. Stoichiometric reactions support the generation of a well-organized chiral ammonium hydroxide species (Q+OH-).

Original languageEnglish
Pages (from-to)7178-7182
Number of pages5
JournalChemistry - A European Journal
Volume17
Issue number26
DOIs
Publication statusPublished - Jun 20 2011

Fingerprint

Protonation
Hydrolysis
Esters
Ammonium Hydroxide
Ammonium hydroxide
Catalysts
Enzymes
hydroxide ion

All Science Journal Classification (ASJC) codes

  • Chemistry(all)

Cite this

Catalytic asymmetric hydrolysis : Asymmetric hydrolytic protonation of enol esters catalyzed by phase-transfer catalysts. / Yamamoto, Eiji; Nagai, Ayano; Hamasaki, Akiyuki; Tokunaga, Makoto.

In: Chemistry - A European Journal, Vol. 17, No. 26, 20.06.2011, p. 7178-7182.

Research output: Contribution to journalArticle

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abstract = "Like an enzyme: Asymmetric hydrolysis of enol esters is accomplished by chiral phase-transfer catalysts under biphasic base hydrolysis conditions. Stoichiometric reactions support the generation of a well-organized chiral ammonium hydroxide species (Q+OH-).",
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AU - Tokunaga, Makoto

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