Catalytic deoxygenation of pyridine N-oxides with N-fused porphyrin rhenium complexes

Motoki Toganoh; Keitaro Fujino; Shinya Ikeda; Hiroyuki Furuta

doi:10.1016/j.tetlet.2007.12.117

Catalytic deoxygenation of pyridine N-oxides with N-fused porphyrin rhenium complexes

Motoki Toganoh, Keitaro Fujino, Shinya Ikeda, Hiroyuki Furuta

Research output: Contribution to journal › Article › peer-review

55 Citations (Scopus)

Abstract

Deoxygenation reactions of pyridine N-oxide derivatives catalyzed by N-fused porphyrin rhenium(VII) trioxo complexes are developed, affording the corresponding pyridine derivatives in quantitative yields with excellent turnover numbers up to 340,000.

Original language	English
Pages (from-to)	1488-1491
Number of pages	4
Journal	Tetrahedron Letters
Volume	49
Issue number	9
DOIs	https://doi.org/10.1016/j.tetlet.2007.12.117
Publication status	Published - Feb 25 2008

All Science Journal Classification (ASJC) codes

Biochemistry
Drug Discovery
Organic Chemistry

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10.1016/j.tetlet.2007.12.117

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title = "Catalytic deoxygenation of pyridine N-oxides with N-fused porphyrin rhenium complexes",

abstract = "Deoxygenation reactions of pyridine N-oxide derivatives catalyzed by N-fused porphyrin rhenium(VII) trioxo complexes are developed, affording the corresponding pyridine derivatives in quantitative yields with excellent turnover numbers up to 340,000.",

author = "Motoki Toganoh and Keitaro Fujino and Shinya Ikeda and Hiroyuki Furuta",

note = "Funding Information: The present work was supported by the Grant-in-Aid for Scientific Research (16350024 and 19750036) and the Global COE Program {\textquoteleft}Science for Future Molecular Systems{\textquoteright} from the Ministry of Education, Culture, Science, Sports and Technology of Japan, and PRESTO from JST, Japan. ",

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T1 - Catalytic deoxygenation of pyridine N-oxides with N-fused porphyrin rhenium complexes

AU - Toganoh, Motoki

AU - Fujino, Keitaro

AU - Ikeda, Shinya

AU - Furuta, Hiroyuki

N1 - Funding Information: The present work was supported by the Grant-in-Aid for Scientific Research (16350024 and 19750036) and the Global COE Program ‘Science for Future Molecular Systems’ from the Ministry of Education, Culture, Science, Sports and Technology of Japan, and PRESTO from JST, Japan.

PY - 2008/2/25

Y1 - 2008/2/25

N2 - Deoxygenation reactions of pyridine N-oxide derivatives catalyzed by N-fused porphyrin rhenium(VII) trioxo complexes are developed, affording the corresponding pyridine derivatives in quantitative yields with excellent turnover numbers up to 340,000.

AB - Deoxygenation reactions of pyridine N-oxide derivatives catalyzed by N-fused porphyrin rhenium(VII) trioxo complexes are developed, affording the corresponding pyridine derivatives in quantitative yields with excellent turnover numbers up to 340,000.

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DO - 10.1016/j.tetlet.2007.12.117

M3 - Article

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SN - 0040-4039

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EP - 1491

JO - Tetrahedron Letters

JF - Tetrahedron Letters

IS - 9

ER -

Catalytic deoxygenation of pyridine N-oxides with N-fused porphyrin rhenium complexes

Abstract

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