Catalytic enantioselective synthesis of alkenylhydrosilanes

Kazunobu Igawa; Daisuke Yoshihiro; Nobumasa Ichikawa; Naoto Kokan; Katsuhiko Tomooka

doi:10.1002/anie.201207361

Catalytic enantioselective synthesis of alkenylhydrosilanes

Kazunobu Igawa, Daisuke Yoshihiro, Nobumasa Ichikawa, Naoto Kokan, Katsuhiko Tomooka

Department of Applied Molecular Chemistry

Research output: Contribution to journal › Article › peer-review

84 Citations (Scopus)

Abstract

Asymmetric silanes: A synthesis of nonracemic alkenylhydrosilanes has been developed based on the desymmetrization of a dihydrosilane through alkenylation with an alkyne using an asymmetric catalyst. The alkenylhydrosilane product can be used as a versatile chiral building block for other functionalized nonracemic silanes through the stereoselective conversion of its hydride and/or alkenyl moiety.

Original language	English
Pages (from-to)	12745-12748
Number of pages	4
Journal	Angewandte Chemie - International Edition
Volume	51
Issue number	51
DOIs	https://doi.org/10.1002/anie.201207361
Publication status	Published - Dec 14 2012

All Science Journal Classification (ASJC) codes

Catalysis
Chemistry(all)

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abstract = "Asymmetric silanes: A synthesis of nonracemic alkenylhydrosilanes has been developed based on the desymmetrization of a dihydrosilane through alkenylation with an alkyne using an asymmetric catalyst. The alkenylhydrosilane product can be used as a versatile chiral building block for other functionalized nonracemic silanes through the stereoselective conversion of its hydride and/or alkenyl moiety.",

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AU - Igawa, Kazunobu

AU - Yoshihiro, Daisuke

AU - Ichikawa, Nobumasa

AU - Kokan, Naoto

AU - Tomooka, Katsuhiko

PY - 2012/12/14

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AB - Asymmetric silanes: A synthesis of nonracemic alkenylhydrosilanes has been developed based on the desymmetrization of a dihydrosilane through alkenylation with an alkyne using an asymmetric catalyst. The alkenylhydrosilane product can be used as a versatile chiral building block for other functionalized nonracemic silanes through the stereoselective conversion of its hydride and/or alkenyl moiety.

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Catalytic enantioselective synthesis of alkenylhydrosilanes

Abstract

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