Catalytic enantioselective synthesis of alkenylhydrosilanes

Kazunobu Igawa, Daisuke Yoshihiro, Nobumasa Ichikawa, Naoto Kokan, Katsuhiko Tomooka

Research output: Contribution to journalArticle

39 Citations (Scopus)

Abstract

Asymmetric silanes: A synthesis of nonracemic alkenylhydrosilanes has been developed based on the desymmetrization of a dihydrosilane through alkenylation with an alkyne using an asymmetric catalyst. The alkenylhydrosilane product can be used as a versatile chiral building block for other functionalized nonracemic silanes through the stereoselective conversion of its hydride and/or alkenyl moiety.

Original languageEnglish
Pages (from-to)12745-12748
Number of pages4
JournalAngewandte Chemie - International Edition
Volume51
Issue number51
DOIs
Publication statusPublished - Dec 14 2012

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Silanes
Alkenylation
Alkynes
Hydrides
Catalysts

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Chemistry(all)

Cite this

Catalytic enantioselective synthesis of alkenylhydrosilanes. / Igawa, Kazunobu; Yoshihiro, Daisuke; Ichikawa, Nobumasa; Kokan, Naoto; Tomooka, Katsuhiko.

In: Angewandte Chemie - International Edition, Vol. 51, No. 51, 14.12.2012, p. 12745-12748.

Research output: Contribution to journalArticle

Igawa, Kazunobu ; Yoshihiro, Daisuke ; Ichikawa, Nobumasa ; Kokan, Naoto ; Tomooka, Katsuhiko. / Catalytic enantioselective synthesis of alkenylhydrosilanes. In: Angewandte Chemie - International Edition. 2012 ; Vol. 51, No. 51. pp. 12745-12748.
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