Catalytic Enantioselective Synthesis of Planar-Chiral Cyclic Amides Based on a Pd-Catalyzed Asymmetric Allylic Substitution Reaction

Kazunobu Igawa; Nobumasa Ichikawa; Yusuke Ano; Keisuke Katanoda; Masato Ito; Toshiyuki Akiyama; Katsuhiko Tomooka

doi:10.1021/jacs.5b04340

Catalytic Enantioselective Synthesis of Planar-Chiral Cyclic Amides Based on a Pd-Catalyzed Asymmetric Allylic Substitution Reaction

Kazunobu Igawa, Nobumasa Ichikawa, Yusuke Ano, Keisuke Katanoda, Masato Ito, Toshiyuki Akiyama, Katsuhiko Tomooka

Department of Applied Molecular Chemistry

Research output: Contribution to journal › Article › peer-review

15 Citations (Scopus)

Abstract

The highly enantioselective synthesis of planar-chiral nine-membered cyclic amides was achieved by the Pd-catalyzed asymmetric allylic cyclization of achiral linear precursors in the presence of a catalytic amount of chiral ligand.

Original language	English
Pages (from-to)	7294-7297
Number of pages	4
Journal	Journal of the American Chemical Society
Volume	137
Issue number	23
DOIs	https://doi.org/10.1021/jacs.5b04340
Publication status	Published - Jun 17 2015

All Science Journal Classification (ASJC) codes

Catalysis
Chemistry(all)
Biochemistry
Colloid and Surface Chemistry

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10.1021/jacs.5b04340

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title = "Catalytic Enantioselective Synthesis of Planar-Chiral Cyclic Amides Based on a Pd-Catalyzed Asymmetric Allylic Substitution Reaction",

abstract = "The highly enantioselective synthesis of planar-chiral nine-membered cyclic amides was achieved by the Pd-catalyzed asymmetric allylic cyclization of achiral linear precursors in the presence of a catalytic amount of chiral ligand.",

author = "Kazunobu Igawa and Nobumasa Ichikawa and Yusuke Ano and Keisuke Katanoda and Masato Ito and Toshiyuki Akiyama and Katsuhiko Tomooka",

note = "Publisher Copyright: {\textcopyright} 2015 American Chemical Society.",

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T1 - Catalytic Enantioselective Synthesis of Planar-Chiral Cyclic Amides Based on a Pd-Catalyzed Asymmetric Allylic Substitution Reaction

AU - Igawa, Kazunobu

AU - Ichikawa, Nobumasa

AU - Ano, Yusuke

AU - Katanoda, Keisuke

AU - Ito, Masato

AU - Akiyama, Toshiyuki

AU - Tomooka, Katsuhiko

PY - 2015/6/17

Y1 - 2015/6/17

N2 - The highly enantioselective synthesis of planar-chiral nine-membered cyclic amides was achieved by the Pd-catalyzed asymmetric allylic cyclization of achiral linear precursors in the presence of a catalytic amount of chiral ligand.

AB - The highly enantioselective synthesis of planar-chiral nine-membered cyclic amides was achieved by the Pd-catalyzed asymmetric allylic cyclization of achiral linear precursors in the presence of a catalytic amount of chiral ligand.

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DO - 10.1021/jacs.5b04340

M3 - Article

AN - SCOPUS:84934900764

SN - 0002-7863

VL - 137

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JO - Journal of the American Chemical Society

JF - Journal of the American Chemical Society

IS - 23

ER -

Catalytic Enantioselective Synthesis of Planar-Chiral Cyclic Amides Based on a Pd-Catalyzed Asymmetric Allylic Substitution Reaction

Abstract

All Science Journal Classification (ASJC) codes

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