Catalytic Enantioselective Synthesis of Planar-Chiral Cyclic Amides Based on a Pd-Catalyzed Asymmetric Allylic Substitution Reaction

Kazunobu Igawa, Nobumasa Ichikawa, Yusuke Ano, Keisuke Katanoda, Masato Ito, Toshiyuki Akiyama, Katsuhiko Tomooka

Research output: Contribution to journalArticle

9 Citations (Scopus)

Abstract

The highly enantioselective synthesis of planar-chiral nine-membered cyclic amides was achieved by the Pd-catalyzed asymmetric allylic cyclization of achiral linear precursors in the presence of a catalytic amount of chiral ligand.

Original languageEnglish
Pages (from-to)7294-7297
Number of pages4
JournalJournal of the American Chemical Society
Volume137
Issue number23
DOIs
Publication statusPublished - Jun 17 2015

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Cyclization
Amides
Substitution reactions
Ligands

All Science Journal Classification (ASJC) codes

  • Chemistry(all)
  • Catalysis
  • Biochemistry
  • Colloid and Surface Chemistry

Cite this

Catalytic Enantioselective Synthesis of Planar-Chiral Cyclic Amides Based on a Pd-Catalyzed Asymmetric Allylic Substitution Reaction. / Igawa, Kazunobu; Ichikawa, Nobumasa; Ano, Yusuke; Katanoda, Keisuke; Ito, Masato; Akiyama, Toshiyuki; Tomooka, Katsuhiko.

In: Journal of the American Chemical Society, Vol. 137, No. 23, 17.06.2015, p. 7294-7297.

Research output: Contribution to journalArticle

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AU - Katanoda, Keisuke

AU - Ito, Masato

AU - Akiyama, Toshiyuki

AU - Tomooka, Katsuhiko

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