Catalytic functionalization of methyl group on silicon: Iridium-catalyzed C(sp3)-H borylation of methylchlorosilanes

Toshimichi Ohmura, Takeru Torigoe, Michinori Suginome

Research output: Contribution to journalArticle

63 Citations (Scopus)

Abstract

A methyl group of methylchlorosilanes undergoes C-H borylation in an iridium-catalyzed reaction with bis(pinacolato)diboron in cyclohexane at 80 °C, giving (borylmethyl)chlorosilanes selectively.

Original languageEnglish
Pages (from-to)17416-17419
Number of pages4
JournalJournal of the American Chemical Society
Volume134
Issue number42
DOIs
Publication statusPublished - Oct 24 2012

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Chemistry(all)
  • Biochemistry
  • Colloid and Surface Chemistry

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