Catalytic Reduction of Molecular Dinitrogen to Ammonia and Hydrazine Using Vanadium Complexes

Yoshiya Sekiguchi, Kazuya Arashiba, Hiromasa Tanaka, Aya Eizawa, Kazunari Nakajima, Kazunari Yoshizawa, Yoshiaki Nishibayashi

Research output: Contribution to journalArticle

24 Citations (Scopus)

Abstract

Newly designed and prepared vanadium complexes bearing anionic pyrrole-based PNP-type pincer and aryloxy ligands were found to work as effective catalysts for the direct conversion of molecular dinitrogen into ammonia and hydrazine under mild reaction conditions. This is the first successful example of vanadium-catalyzed dinitrogen reduction under mild reaction conditions.

Original languageEnglish
Pages (from-to)9064-9068
Number of pages5
JournalAngewandte Chemie - International Edition
Volume57
Issue number29
DOIs
Publication statusPublished - Jul 16 2018

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hydrazine
Vanadium
Hydrazine
Ammonia
Bearings (structural)
Pyrroles
Ligands
Catalysts

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Chemistry(all)

Cite this

Catalytic Reduction of Molecular Dinitrogen to Ammonia and Hydrazine Using Vanadium Complexes. / Sekiguchi, Yoshiya; Arashiba, Kazuya; Tanaka, Hiromasa; Eizawa, Aya; Nakajima, Kazunari; Yoshizawa, Kazunari; Nishibayashi, Yoshiaki.

In: Angewandte Chemie - International Edition, Vol. 57, No. 29, 16.07.2018, p. 9064-9068.

Research output: Contribution to journalArticle

Sekiguchi, Yoshiya ; Arashiba, Kazuya ; Tanaka, Hiromasa ; Eizawa, Aya ; Nakajima, Kazunari ; Yoshizawa, Kazunari ; Nishibayashi, Yoshiaki. / Catalytic Reduction of Molecular Dinitrogen to Ammonia and Hydrazine Using Vanadium Complexes. In: Angewandte Chemie - International Edition. 2018 ; Vol. 57, No. 29. pp. 9064-9068.
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