Cathode Properties of Perovskite-type NaMF3 (M = Fe, Mn, and Co) Prepared by Mechanical Ball Milling for Sodium-ion Battery

Ayuko Kitajou, Yuji Ishado, Tomoki Yamashita, Hiroyoshi Momida, Tamio Oguchi, Shigeto Okada

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3 Citations (Scopus)

Abstract

NaFeF3 and NaMnF3 are promising cathode materials for sodium-ion batteries due to their low cost, low environmental impact and large theoretical capacity. NaCoF3 also has attracted attention as the high voltage cathode material for sodium-ion batteries. But, these ionic NaMF3 (M = Fe, Mn and Co) compounds have insulating character. To improve the lower electronic conductivity, two-step ball-milling with carbon was performed to obtain a uniform NaMF3 and carbon composite. The rechargeable capacity of NaFeF3 was 169 mAh g−1, and its energy density was over 500 Wh kg−1, which is the highest among the reported iron-based cathode materials for sodium-ion batteries. In addition, the experimental voltage for NaMnF3 was ca. 3.4 V, and the voltages for NaMF3 (M = Fe and Mn) calculated by the DFT method corresponded well with the experimental results for NaFeF3 and NaMnF3.

Original languageEnglish
Pages (from-to)424-429
Number of pages6
JournalElectrochimica Acta
Volume245
DOIs
Publication statusPublished - Aug 10 2017

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All Science Journal Classification (ASJC) codes

  • Chemical Engineering(all)
  • Electrochemistry

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