Cellulose i nanolayers designed by self-assembly of its thiosemicarbazone on a gold substrate

Research output: Contribution to journalArticle

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Abstract

Cellulose I nanolayers were designed by self-assembly of its thiosemicarbazide (TSC) on a gold substrate, used for selectively labeling the reducing end of cellulose in an amine N-oxide solvent system. The XPS studies show that the TSC derivatization of cellulose and the surface treatment of the Au substrate with the cellulose-TSC/NMMO solution provide a stable,cellulosic self-assembled monolayer (SAM). The scratched flakes of Au substrate confirms polycrystalline structure while a major diffraction pattern is consistent with an Au plane. The results show that the cellulosic nanolayer possess a structured morphology consisting of the cellulose-TSC derivatives fixed onto the Au substrate and gathered together in a fibrous form. The results also report the formation of short-chain cellulose I assemblies as powdery aggregates and the formation of regenerate cellulose mixture of cellulose I fibrils and cellulose II aggregates.

Original languageEnglish
Pages (from-to)3368-3370
Number of pages3
JournalAdvanced Materials
Volume19
Issue number20
DOIs
Publication statusPublished - Oct 19 2007

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Thiosemicarbazones
Cellulose
Gold
Self assembly
Substrates
Cellulose derivatives
Self assembled monolayers
Oxides
Labeling
Diffraction patterns
Amines
Surface treatment
X ray photoelectron spectroscopy
thiosemicarbazide

All Science Journal Classification (ASJC) codes

  • Materials Science(all)
  • Mechanics of Materials
  • Mechanical Engineering

Cite this

Cellulose i nanolayers designed by self-assembly of its thiosemicarbazone on a gold substrate. / Yokota, Shingo; Kitaoka, Takuya; Sugiyama, Junji; Wariishi, Hiroyuki.

In: Advanced Materials, Vol. 19, No. 20, 19.10.2007, p. 3368-3370.

Research output: Contribution to journalArticle

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