Characterization of a Dinuclear MnV=O Complex and Its Efficient Evolution of O2 in the Presence of Water

Yuichi Shimazaki, Taro Nagano, Hironori Takesue, Bao Hui Ye, Fumito Tani, Yoshinori Naruta

Research output: Contribution to journalArticlepeer-review

204 Citations (Scopus)

Abstract

A high valent MnV=O porphyrin dimer is prepared by peracid oxidation or an MnIII dimer under basic conditions at room temperature (see scheme; mCPBA = m-chloroperbenzoic acid). The addition of an acid to a solution of the MnV=O complex results in quantitative dioxygen evolution. Water and/or hydroxide ions are the sources of both the oxo ligand and the evolved dioxygen.

Original languageEnglish
Pages (from-to)98-100
Number of pages3
JournalAngewandte Chemie - International Edition
Volume43
Issue number1
DOIs
Publication statusPublished - Dec 22 2004

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Chemistry(all)

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