Characterization of imidazolate-bridged Cu(II)-Zn(II) heterodinuclear and Cu(II)-Cu(II) homodinuclear hydroperoxo complexes as reaction intermediate models of Cu,Zn-SOD

Hideki Ohtsu, Shinobu Itoh, Shigenori Nagatomo, Teizo Kitagawa, Seiji Ogo, Yoshihito Watanabe, Shunichi Fukuzumi

Research output: Contribution to journalArticle

30 Citations (Scopus)

Abstract

Imidazolate-bridged Cu(II)-Zn(II) heterodinuclear and Cu(II)-Cu(II) homodinuclear hydroperoxo complexes are generated in the reactions between imidazolate-bridged heterodinuclear and homodinuclear complexes and H2O2 in the presence of triethylamine base and characterized spectroscopically as reaction intermediate models of Cu,Zn-SOD.

Original languageEnglish
Pages (from-to)1051-1052
Number of pages2
JournalChemical Communications
Issue number12
DOIs
Publication statusPublished - Jun 21 2000
Externally publishedYes

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Chemistry(all)
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry

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