Characterizations of divalent lanthanoid iodides in tetrahydrofuran by UV-Vis, fluorescence and ESR spectroscopy

Yoshihiro Okaue, Toshiyuki Isobe

Research output: Contribution to journalArticle

30 Citations (Scopus)

Abstract

Spectrochemical properties of LnI2 (Ln = Sm, Eu, Yb) prepared with lanthanoid metal and diiodoethane in THF were characterized by means of UV-Vis, fluorescence and ESR spectroscopy. A comparative investigation has also been made concerning LnI3 (Ln= LaLu) and the Grignard-type compounds RLnI (R = Et, Ph; Ln = Eu, Yb). LnI2 (Ln = Sm, Eu, Yb) was also prepared from reaction of lanthanoid metal and iodine in THF.

Original languageEnglish
Pages (from-to)143-146
Number of pages4
JournalInorganica Chimica Acta
Volume144
Issue number1
DOIs
Publication statusPublished - Apr 1 1988

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Lanthanoid Series Elements
Fluorescence Spectrometry
Iodides
tetrahydrofuran
iodides
Paramagnetic resonance
Metals
Fluorescence
Spectroscopy
fluorescence
Iodine
metals
spectroscopy
iodine
methylene iodide

All Science Journal Classification (ASJC) codes

  • Inorganic Chemistry
  • Physical and Theoretical Chemistry
  • Materials Chemistry
  • Biochemistry

Cite this

Characterizations of divalent lanthanoid iodides in tetrahydrofuran by UV-Vis, fluorescence and ESR spectroscopy. / Okaue, Yoshihiro; Isobe, Toshiyuki.

In: Inorganica Chimica Acta, Vol. 144, No. 1, 01.04.1988, p. 143-146.

Research output: Contribution to journalArticle

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