Characterizations of interlayer organic-inorganic nanohybrid of molybdenum trioxide with polyaniline and poly(o-anisidine)

Toshio Itoh, Ichiro Matsubara, Woosuck Shin, Noriya Izu, Maiko Nishibori

Research output: Contribution to journalArticle

9 Citations (Scopus)

Abstract

Characterizations of layered MoO3 host with interlayer polyaniline (PANI) and poly(o-anisidine) (PoANIS), i.e. (PANI)xMoO3 and (PoANIS)xMoO3, respectively, have been carried out by means of X-ray diffraction (XRD), infrared (IR) spectra, thermogravimetry (TG), and solid-state nuclear magnetic resonance (NMR) analyses. The guest organic components, i.e. PANI and PoANIS, are accommodated into MoO3 interlayers by ion-exchange process. From these detailed characterization studies, it is found that the interlayer PANI and PoANIS chains have neutralized units as well as cationic units. Moreover, the (PANI)xMoO3 and (PoANIS)xMoO3 hybrids have enough interlayer spaces due to almost perpendicular orientation of benzene ring into PANI and PoANIS chains to the MoO3 layer.

Original languageEnglish
Pages (from-to)115-119
Number of pages5
JournalMaterials Chemistry and Physics
Volume110
Issue number1
DOIs
Publication statusPublished - Jul 15 2008
Externally publishedYes

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Polyaniline
Molybdenum
molybdenum
interlayers
thermogravimetry
infrared spectra
benzene
Thermogravimetric analysis
Benzene
solid state
Ion exchange
nuclear magnetic resonance
Nuclear magnetic resonance
2-anisidine
polyaniline
molybdenum trioxide
rings
Infrared radiation
X ray diffraction
diffraction

All Science Journal Classification (ASJC) codes

  • Materials Science(all)
  • Condensed Matter Physics

Cite this

Characterizations of interlayer organic-inorganic nanohybrid of molybdenum trioxide with polyaniline and poly(o-anisidine). / Itoh, Toshio; Matsubara, Ichiro; Shin, Woosuck; Izu, Noriya; Nishibori, Maiko.

In: Materials Chemistry and Physics, Vol. 110, No. 1, 15.07.2008, p. 115-119.

Research output: Contribution to journalArticle

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AU - Itoh, Toshio

AU - Matsubara, Ichiro

AU - Shin, Woosuck

AU - Izu, Noriya

AU - Nishibori, Maiko

PY - 2008/7/15

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AB - Characterizations of layered MoO3 host with interlayer polyaniline (PANI) and poly(o-anisidine) (PoANIS), i.e. (PANI)xMoO3 and (PoANIS)xMoO3, respectively, have been carried out by means of X-ray diffraction (XRD), infrared (IR) spectra, thermogravimetry (TG), and solid-state nuclear magnetic resonance (NMR) analyses. The guest organic components, i.e. PANI and PoANIS, are accommodated into MoO3 interlayers by ion-exchange process. From these detailed characterization studies, it is found that the interlayer PANI and PoANIS chains have neutralized units as well as cationic units. Moreover, the (PANI)xMoO3 and (PoANIS)xMoO3 hybrids have enough interlayer spaces due to almost perpendicular orientation of benzene ring into PANI and PoANIS chains to the MoO3 layer.

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