Charge-discharge and high temperature reaction of LiCoO2 in ionic liquid electrolytes based on cyano-substituted quaternary ammonium cation

Minato Egashira, Maika Tanaka-Nakagawa, Izumi Watanabe, Shigeto Okada, Jun ichi Yamaki

Research output: Contribution to journalArticlepeer-review

44 Citations (Scopus)

Abstract

The charge-discharge performance of LiCoO2 positive electrode was observed in a mixed electrolyte system consisting of two ionic liquids: cyano-substituted quaternary ammonium bis(trifluoromethane)sulfoneimide (TFSI) and a same-anion salt of 1-ethyl-3-methyl imidazolium (EMI). The positive electrode exhibited a discharge capacity rather close to the theoretical one when N,N,N,N-cyanoethyl trimethyl ammonium salt was applied. Differential scanning calorimetry (DSC) studies revealed that these electrolytes exhibited exotherm only around 260 °C, 50 °C higher than conventional carbonate-based electrolytes. This is the first attempt to reveal the thermal stability of ionic liquid electrolyte under a practical situation.

Original languageEnglish
Pages (from-to)1387-1390
Number of pages4
JournalJournal of Power Sources
Volume160
Issue number2 SPEC. ISS.
DOIs
Publication statusPublished - Oct 6 2006

All Science Journal Classification (ASJC) codes

  • Renewable Energy, Sustainability and the Environment
  • Energy Engineering and Power Technology
  • Physical and Theoretical Chemistry
  • Electrical and Electronic Engineering

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