Charge separation on the micelle surface as evidence for a multi-step hydrogen transfer mechanism in NADH model reduction

Seiji Shinkai, Takaharu Tsuno, Osamu Manabe

Research output: Contribution to journalArticle

15 Citations (Scopus)

Abstract

Reductive desulphonation of 2,4,6-trinitrobenzenesulphonate by N-dodecyl-1 -benzyl-1,4-dihydronicotinamide bound to the sodium dodecyl sulphate micelle in D2O solution gave 1,3,5-trinitrobenzene which contained 4.6-5.1% of deuterium; the result indicates that the reaction proceeds through multi-step hydrogen transfer via a radical ion-pair intermediate and the micelle surface is capable of dissociating the radical ion pair.

Original languageEnglish
Pages (from-to)592-594
Number of pages3
JournalJournal of the Chemical Society, Chemical Communications
Issue number11
DOIs
Publication statusPublished - Jan 1 1982
Externally publishedYes

All Science Journal Classification (ASJC) codes

  • Molecular Medicine

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