Chemical Characterization of a Volatile Dubnium Compound, DbOCl3

Nadine M. Chiera, Tetsuya K. Sato, Robert Eichler, Tomohiro Tomitsuka, Masato Asai, Sadia Adachi, Rugard Dressler, Kentaro Hirose, Hiroki Inoue, Yuta Ito, Ayuna Kashihara, Hiroyuki Makii, Katsuhisa Nishio, Minoru Sakama, Kaori Shirai, Hayato Suzuki, Katsuyuki Tokoi, Kazuaki Tsukada, Eisuke Watanabe, Yuichiro Nagame

Research output: Contribution to journalArticlepeer-review

Abstract

The formation and the chemical characterization of single atoms of dubnium (Db, element 105), in the form of its volatile oxychloride, was investigated using the on-line gas phase chromatography technique, in the temperature range 350–600 °C. Under the exactly same chemical conditions, comparative studies with the lighter homologues of Group 5 in the Periodic Table clearly indicate the volatility sequence being NbOCl3 > TaOCl3 ≥ DbOCl3. From the obtained experimental results, thermochemical data for DbOCl3 were derived. The present study delivers reliable experimental information for theoretical calculations on chemical properties of transactinides.

Original languageEnglish
Pages (from-to)17871-17874
Number of pages4
JournalAngewandte Chemie - International Edition
Volume60
Issue number33
DOIs
Publication statusPublished - Aug 9 2021

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Chemistry(all)

Fingerprint

Dive into the research topics of 'Chemical Characterization of a Volatile Dubnium Compound, DbOCl<sub>3</sub>'. Together they form a unique fingerprint.

Cite this