Abstract
The introduction of the CN group onto a diamond surface was attempted using diacyl peroxides with CN group-containing compounds. When acetonitrile was used as solvent for the radical reaction process, the CN group was introduced onto the diamond surface, however when benzonitrile was used no CN group was introduced. The mechanism for introduction of the CN group onto the diamond surface is proposed to be as follows: Acetonitrile includes an alkyl group in its structure. The radical species derived from the diacyl peroxide appears to abstract the hydrogen atom from the alkyl group, with the radical species generated from acetonitrile then reacting with the diamond surface activated by the radical species derived from the diacyl peroxide. However, for benzonitrile, no hydrogen abstraction reaction can proceed as it has no alkyl group.
| Original language | English |
|---|---|
| Pages (from-to) | 3881-3886 |
| Number of pages | 6 |
| Journal | Physical Chemistry Chemical Physics |
| Volume | 4 |
| Issue number | 15 |
| DOIs | |
| Publication status | Published - Jan 1 2002 |
Fingerprint
All Science Journal Classification (ASJC) codes
- Physics and Astronomy(all)
- Physical and Theoretical Chemistry
Cite this
Chemical modification of diamond surface using a diacyl peroxide as radical initiator and CN group-containing compounds for the introduction of the CN group. / Tsubota, Toshiki; Ida, Shintaro; Hirabayashi, Osamu; Nagaoka, Shoji; Nagata, Masanori; Matsumoto, Yasumichi.
In: Physical Chemistry Chemical Physics, Vol. 4, No. 15, 01.01.2002, p. 3881-3886.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Chemical modification of diamond surface using a diacyl peroxide as radical initiator and CN group-containing compounds for the introduction of the CN group
AU - Tsubota, Toshiki
AU - Ida, Shintaro
AU - Hirabayashi, Osamu
AU - Nagaoka, Shoji
AU - Nagata, Masanori
AU - Matsumoto, Yasumichi
PY - 2002/1/1
Y1 - 2002/1/1
N2 - The introduction of the CN group onto a diamond surface was attempted using diacyl peroxides with CN group-containing compounds. When acetonitrile was used as solvent for the radical reaction process, the CN group was introduced onto the diamond surface, however when benzonitrile was used no CN group was introduced. The mechanism for introduction of the CN group onto the diamond surface is proposed to be as follows: Acetonitrile includes an alkyl group in its structure. The radical species derived from the diacyl peroxide appears to abstract the hydrogen atom from the alkyl group, with the radical species generated from acetonitrile then reacting with the diamond surface activated by the radical species derived from the diacyl peroxide. However, for benzonitrile, no hydrogen abstraction reaction can proceed as it has no alkyl group.
AB - The introduction of the CN group onto a diamond surface was attempted using diacyl peroxides with CN group-containing compounds. When acetonitrile was used as solvent for the radical reaction process, the CN group was introduced onto the diamond surface, however when benzonitrile was used no CN group was introduced. The mechanism for introduction of the CN group onto the diamond surface is proposed to be as follows: Acetonitrile includes an alkyl group in its structure. The radical species derived from the diacyl peroxide appears to abstract the hydrogen atom from the alkyl group, with the radical species generated from acetonitrile then reacting with the diamond surface activated by the radical species derived from the diacyl peroxide. However, for benzonitrile, no hydrogen abstraction reaction can proceed as it has no alkyl group.
UR - http://www.scopus.com/inward/record.url?scp=0036378328&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=0036378328&partnerID=8YFLogxK
U2 - 10.1039/b202345h
DO - 10.1039/b202345h
M3 - Article
VL - 4
SP - 3881
EP - 3886
JO - Physical Chemistry Chemical Physics
JF - Physical Chemistry Chemical Physics
SN - 1463-9076
IS - 15
ER -