Chemical modification of diamond surface with CH3(CH2)nCOOH using benzoyl peroxide

Toshiki Tsubota, Shunsuke Tanii, Shintaro Ida, Masanori Nagata, Yasumichi Matsumoto

Research output: Contribution to journalArticle

26 Citations (Scopus)

Abstract

The chemical reactivity of a hydrogenated diamond surface with carboxylic acid [HCOOH, CH3(CH2)nCOOH (0 < n < 16)] in benzoyl peroxide containing solvent was investigated. The diamond surface modified with acetic acid was stable against severe conditions. The chemical reaction rate of the modification of the diamond surface was calculated based on experimental results. The peak intensity assigned to the C-H bond was determined by the kind of carboxylic acid used. The chemical reaction described in this study is very interesting because it can be used to design the chemical condition of the diamond surface. This chemical reaction constitutes a promising method for chemically modifying the diamond surface.

Original languageEnglish
Pages (from-to)1474-1480
Number of pages7
JournalPhysical Chemistry Chemical Physics
Volume5
Issue number7
DOIs
Publication statusPublished - Apr 1 2003
Externally publishedYes

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Benzoyl Peroxide
Diamond
Chemical modification
peroxides
diamonds
Chemical reactions
chemical reactions
Carboxylic Acids
carboxylic acids
Chemical reactivity
acetic acid
Acetic Acid
Reaction rates
reaction kinetics
reactivity

All Science Journal Classification (ASJC) codes

  • Physical and Theoretical Chemistry
  • Atomic and Molecular Physics, and Optics

Cite this

Chemical modification of diamond surface with CH3(CH2)nCOOH using benzoyl peroxide. / Tsubota, Toshiki; Tanii, Shunsuke; Ida, Shintaro; Nagata, Masanori; Matsumoto, Yasumichi.

In: Physical Chemistry Chemical Physics, Vol. 5, No. 7, 01.04.2003, p. 1474-1480.

Research output: Contribution to journalArticle

Tsubota, Toshiki ; Tanii, Shunsuke ; Ida, Shintaro ; Nagata, Masanori ; Matsumoto, Yasumichi. / Chemical modification of diamond surface with CH3(CH2)nCOOH using benzoyl peroxide. In: Physical Chemistry Chemical Physics. 2003 ; Vol. 5, No. 7. pp. 1474-1480.
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