Chemical modification of hydrogenated diamond surface using benzoyl peroxides

Toshiki Tsubota; Osamu Hirabayashi; Shintaro Ida; Shoji Nagaoka; Masanori Nagata; Yasumichi Matsumoto

doi:10.1039/b107349b

Chemical modification of hydrogenated diamond surface using benzoyl peroxides

Toshiki Tsubota, Osamu Hirabayashi, Shintaro Ida, Shoji Nagaoka, Masanori Nagata, Yasumichi Matsumoto

Research output: Contribution to journal › Article › peer-review

23 Citations (Scopus)

Abstract

The chemical reaction of a hydrogenated diamond surface with the radical initiator benzoyl peroxide was performed in order to investigate the reactivity of the diamond surface. It was found that the hydrogen atoms on the diamond surface are abstracted by the radical species generated from benzoyl peroxide. The reaction rate was calculated from the experimental data. The hydrogen abstracted diamond surface reacts with radical species generated from the benzoyl peroxide, not with the solvent.

Original language	English
Pages (from-to)	806-811
Number of pages	6
Journal	Physical Chemistry Chemical Physics
Volume	4
Issue number	5
DOIs	https://doi.org/10.1039/b107349b
Publication status	Published - Jan 1 2002

All Science Journal Classification (ASJC) codes

Physics and Astronomy(all)
Physical and Theoretical Chemistry

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10.1039/b107349b

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abstract = "The chemical reaction of a hydrogenated diamond surface with the radical initiator benzoyl peroxide was performed in order to investigate the reactivity of the diamond surface. It was found that the hydrogen atoms on the diamond surface are abstracted by the radical species generated from benzoyl peroxide. The reaction rate was calculated from the experimental data. The hydrogen abstracted diamond surface reacts with radical species generated from the benzoyl peroxide, not with the solvent.",

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AU - Tsubota, Toshiki

AU - Hirabayashi, Osamu

AU - Ida, Shintaro

AU - Nagaoka, Shoji

AU - Nagata, Masanori

AU - Matsumoto, Yasumichi

PY - 2002/1/1

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N2 - The chemical reaction of a hydrogenated diamond surface with the radical initiator benzoyl peroxide was performed in order to investigate the reactivity of the diamond surface. It was found that the hydrogen atoms on the diamond surface are abstracted by the radical species generated from benzoyl peroxide. The reaction rate was calculated from the experimental data. The hydrogen abstracted diamond surface reacts with radical species generated from the benzoyl peroxide, not with the solvent.

AB - The chemical reaction of a hydrogenated diamond surface with the radical initiator benzoyl peroxide was performed in order to investigate the reactivity of the diamond surface. It was found that the hydrogen atoms on the diamond surface are abstracted by the radical species generated from benzoyl peroxide. The reaction rate was calculated from the experimental data. The hydrogen abstracted diamond surface reacts with radical species generated from the benzoyl peroxide, not with the solvent.

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Chemical modification of hydrogenated diamond surface using benzoyl peroxides

Abstract

All Science Journal Classification (ASJC) codes

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