Chemical modification of hydrogenated diamond surface using benzoyl peroxides

Toshiki Tsubota, Osamu Hirabayashi, Shintaro Ida, Shoji Nagaoka, Masanori Nagata, Yasumichi Matsumoto

Research output: Contribution to journalArticle

62 Citations (Scopus)

Abstract

The chemical reaction of a hydrogenated diamond surface with the radical initiator benzoyl peroxide was performed in order to investigate the reactivity of the diamond surface. It was found that the hydrogen atoms on the diamond surface are abstracted by the radical species generated from benzoyl peroxide. The reaction rate was calculated from the experimental data. The hydrogen abstracted diamond surface reacts with radical species generated from the benzoyl peroxide, not with the solvent.

Original languageEnglish
Pages (from-to)806-811
Number of pages6
JournalPhysical Chemistry Chemical Physics
Volume4
Issue number5
DOIs
Publication statusPublished - Jan 1 2002

Fingerprint

Benzoyl Peroxide
Diamond
Chemical modification
peroxides
diamonds
Hydrogen
initiators
Reaction rates
Chemical reactions
hydrogen atoms
chemical reactions
reaction kinetics
reactivity
Atoms
hydrogen

All Science Journal Classification (ASJC) codes

  • Physics and Astronomy(all)
  • Physical and Theoretical Chemistry

Cite this

Tsubota, T., Hirabayashi, O., Ida, S., Nagaoka, S., Nagata, M., & Matsumoto, Y. (2002). Chemical modification of hydrogenated diamond surface using benzoyl peroxides. Physical Chemistry Chemical Physics, 4(5), 806-811. https://doi.org/10.1039/b107349b

Chemical modification of hydrogenated diamond surface using benzoyl peroxides. / Tsubota, Toshiki; Hirabayashi, Osamu; Ida, Shintaro; Nagaoka, Shoji; Nagata, Masanori; Matsumoto, Yasumichi.

In: Physical Chemistry Chemical Physics, Vol. 4, No. 5, 01.01.2002, p. 806-811.

Research output: Contribution to journalArticle

Tsubota, T, Hirabayashi, O, Ida, S, Nagaoka, S, Nagata, M & Matsumoto, Y 2002, 'Chemical modification of hydrogenated diamond surface using benzoyl peroxides', Physical Chemistry Chemical Physics, vol. 4, no. 5, pp. 806-811. https://doi.org/10.1039/b107349b
Tsubota T, Hirabayashi O, Ida S, Nagaoka S, Nagata M, Matsumoto Y. Chemical modification of hydrogenated diamond surface using benzoyl peroxides. Physical Chemistry Chemical Physics. 2002 Jan 1;4(5):806-811. https://doi.org/10.1039/b107349b
Tsubota, Toshiki ; Hirabayashi, Osamu ; Ida, Shintaro ; Nagaoka, Shoji ; Nagata, Masanori ; Matsumoto, Yasumichi. / Chemical modification of hydrogenated diamond surface using benzoyl peroxides. In: Physical Chemistry Chemical Physics. 2002 ; Vol. 4, No. 5. pp. 806-811.
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