Chemistry and structure of homoepitaxial SrTiO3 films and their influence on oxide-heterostructure interfaces

M. L. Reinle-Schmitt, C. Cancellieri, A. Cavallaro, G. F. Harrington, S. J. Leake, E. Pomjakushina, J. A. Kilner, P. R. Willmott

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Abstract

The properties of single-crystal SrTiO3 substrates and homoepitaxial SrTiO3 films grown by pulsed laser deposition have been compared, in order to understand the loss of interfacial conductivity when more than a critical thickness of nominally homoepitaxial SrTiO3 is inserted between a LaAlO3 film and a SrTiO3 substrate. In particular, the chemical composition and the structure of homoepitaxial SrTiO3 investigated by low-energy ion-scattering and surface X-ray diffraction show that for insulating heterointerfaces, a Sr-excess is present between the LaAlO3 and homoepitaxial SrTiO3. Furthermore, an increase in the out-of-plane lattice constant is observed in LaAlO 3, indicating that the conductivity both with and without insertion of the SrTiO3 thin film originates from a Zener breakdown associated with the polar catastrophe. When more than a critical thickness of homoepitaxial SrTiO3 is inserted between LaAlO3 and SrTiO3, the electrons transferred by the electronic reconstruction are trapped by the formation of a Sr-rich secondary phase and Sr-vacancies. The migration of Sr towards the surface of homoepitaxial SrTiO3 and accompanying loss of interfacial conductivity can be delayed by reducing the Sr-content in the PLD target.

Original languageEnglish
Pages (from-to)2598-2602
Number of pages5
JournalNanoscale
Volume6
Issue number5
DOIs
Publication statusPublished - Mar 7 2014

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All Science Journal Classification (ASJC) codes

  • Materials Science(all)

Cite this

Reinle-Schmitt, M. L., Cancellieri, C., Cavallaro, A., Harrington, G. F., Leake, S. J., Pomjakushina, E., ... Willmott, P. R. (2014). Chemistry and structure of homoepitaxial SrTiO3 films and their influence on oxide-heterostructure interfaces. Nanoscale, 6(5), 2598-2602. https://doi.org/10.1039/c3nr06456e