Chiral ammonium hypoiodite salt-catalyzed enantioselective oxidative cycloetherification to 2-acyl tetrahydrofurans

Muhammet Uyanik; Hiroki Hayashi; Hirokazu Iwata; Kazuaki Ishihara

doi:10.1246/cl.160004

Chiral ammonium hypoiodite salt-catalyzed enantioselective oxidative cycloetherification to 2-acyl tetrahydrofurans

Muhammet Uyanik, Hiroki Hayashi, Hirokazu Iwata, Kazuaki Ishihara

Research output: Contribution to journal › Article › peer-review

18 Citations (Scopus)

Abstract

2-Acyl tetrahydrofuran is a fundamental structure in natural products and pharmaceuticals. We achieved chiral quaternary ammonium hypoiodite salt-catalyzed enantioselective oxidative cycloetherification of δ-hydroxyketone derivatives. The corresponding 2-acyl tetrahydrofurans were obtained in high chemical yield with high enantioselectivity.

Original language	English
Pages (from-to)	353-355
Number of pages	3
Journal	Chemistry Letters
Volume	45
Issue number	3
DOIs	https://doi.org/10.1246/cl.160004
Publication status	Published - Jan 1 2016
Externally published	Yes

All Science Journal Classification (ASJC) codes

Chemistry(all)

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abstract = "2-Acyl tetrahydrofuran is a fundamental structure in natural products and pharmaceuticals. We achieved chiral quaternary ammonium hypoiodite salt-catalyzed enantioselective oxidative cycloetherification of δ-hydroxyketone derivatives. The corresponding 2-acyl tetrahydrofurans were obtained in high chemical yield with high enantioselectivity.",

author = "Muhammet Uyanik and Hiroki Hayashi and Hirokazu Iwata and Kazuaki Ishihara",

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AU - Uyanik, Muhammet

AU - Hayashi, Hiroki

AU - Iwata, Hirokazu

AU - Ishihara, Kazuaki

PY - 2016/1/1

Y1 - 2016/1/1

N2 - 2-Acyl tetrahydrofuran is a fundamental structure in natural products and pharmaceuticals. We achieved chiral quaternary ammonium hypoiodite salt-catalyzed enantioselective oxidative cycloetherification of δ-hydroxyketone derivatives. The corresponding 2-acyl tetrahydrofurans were obtained in high chemical yield with high enantioselectivity.

AB - 2-Acyl tetrahydrofuran is a fundamental structure in natural products and pharmaceuticals. We achieved chiral quaternary ammonium hypoiodite salt-catalyzed enantioselective oxidative cycloetherification of δ-hydroxyketone derivatives. The corresponding 2-acyl tetrahydrofurans were obtained in high chemical yield with high enantioselectivity.

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