Chiral coordinating agent-based enantiocontrol in carbanion reactions

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8 Citations (Scopus)

Abstract

We have been exploring the various enantioselective carbanion reactions induced by the chiral coordinating agent-based asymmetric lithiation protocol. Disclosed herein are the enantioselective carbanion cyclization, SE2 reaction of benzyl lithium, [2,3]- and [1,2]-Wittig rearrangement via the asymmetric lithiation with BuLi complexed with (-)-sparteien or chiral bisoxazoline, as a ligand.

Original languageEnglish
Pages (from-to)322-330
Number of pages9
JournalYuki Gosei Kagaku Kyokaishi/Journal of Synthetic Organic Chemistry
Volume59
Issue number4
DOIs
Publication statusPublished - Jan 1 2001
Externally publishedYes

All Science Journal Classification (ASJC) codes

  • Organic Chemistry

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