Abstract
We have been exploring the various enantioselective carbanion reactions induced by the chiral coordinating agent-based asymmetric lithiation protocol. Disclosed herein are the enantioselective carbanion cyclization, SE2 reaction of benzyl lithium, [2,3]- and [1,2]-Wittig rearrangement via the asymmetric lithiation with BuLi complexed with (-)-sparteien or chiral bisoxazoline, as a ligand.
Original language | English |
---|---|
Pages (from-to) | 322-330 |
Number of pages | 9 |
Journal | Yuki Gosei Kagaku Kyokaishi/Journal of Synthetic Organic Chemistry |
Volume | 59 |
Issue number | 4 |
DOIs | |
Publication status | Published - Jan 1 2001 |
Externally published | Yes |
All Science Journal Classification (ASJC) codes
- Organic Chemistry