Abstract
We have been exploring the various enantioselective carbanion reactions induced by the chiral coordinating agent-based asymmetric lithiation protocol. Disclosed herein are the enantioselective carbanion cyclization, SE2 reaction of benzyl lithium, [2,3]- and [1,2]-Wittig rearrangement via the asymmetric lithiation with BuLi complexed with (-)-sparteien or chiral bisoxazoline, as a ligand.
| Original language | English |
|---|---|
| Pages (from-to) | 322-330 |
| Number of pages | 9 |
| Journal | Yuki Gosei Kagaku Kyokaishi/Journal of Synthetic Organic Chemistry |
| Volume | 59 |
| Issue number | 4 |
| DOIs | |
| Publication status | Published - Jan 1 2001 |
| Externally published | Yes |
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All Science Journal Classification (ASJC) codes
- Organic Chemistry
Cite this
Chiral coordinating agent-based enantiocontrol in carbanion reactions. / Tomooka, K.
In: Yuki Gosei Kagaku Kyokaishi/Journal of Synthetic Organic Chemistry, Vol. 59, No. 4, 01.01.2001, p. 322-330.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Chiral coordinating agent-based enantiocontrol in carbanion reactions
AU - Tomooka, K.
PY - 2001/1/1
Y1 - 2001/1/1
N2 - We have been exploring the various enantioselective carbanion reactions induced by the chiral coordinating agent-based asymmetric lithiation protocol. Disclosed herein are the enantioselective carbanion cyclization, SE2 reaction of benzyl lithium, [2,3]- and [1,2]-Wittig rearrangement via the asymmetric lithiation with BuLi complexed with (-)-sparteien or chiral bisoxazoline, as a ligand.
AB - We have been exploring the various enantioselective carbanion reactions induced by the chiral coordinating agent-based asymmetric lithiation protocol. Disclosed herein are the enantioselective carbanion cyclization, SE2 reaction of benzyl lithium, [2,3]- and [1,2]-Wittig rearrangement via the asymmetric lithiation with BuLi complexed with (-)-sparteien or chiral bisoxazoline, as a ligand.
UR - http://www.scopus.com/inward/record.url?scp=0034917283&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=0034917283&partnerID=8YFLogxK
U2 - 10.5059/yukigoseikyokaishi.59.322
DO - 10.5059/yukigoseikyokaishi.59.322
M3 - Article
AN - SCOPUS:0034917283
VL - 59
SP - 322
EP - 330
JO - Yuki Gosei Kagaku Kyokaishi/Journal of Synthetic Organic Chemistry
JF - Yuki Gosei Kagaku Kyokaishi/Journal of Synthetic Organic Chemistry
SN - 0037-9980
IS - 4
ER -