Chiral dienolate chemistry in remote asymmetric induction: The asymmetric aldol/oxy-Cope strategy for asymmetric synthesis of γ,δ-dichiral α,β-unsaturated acid derivatives

Katsuhiko Tomooka; Atsushi Nagasawa; Shih Yi Wei; Takeshi Nakai

doi:10.1016/S0040-4039(96)02078-3

Chiral dienolate chemistry in remote asymmetric induction: The asymmetric aldol/oxy-Cope strategy for asymmetric synthesis of γ,δ-dichiral α,β-unsaturated acid derivatives

Katsuhiko Tomooka, Atsushi Nagasawa, Shih Yi Wei, Takeshi Nakai

Research output: Contribution to journal › Article › peer-review

38 Citations (Scopus)

Abstract

The asymmetric aldol reaction of the boron dienolate derived from chiral α,β- or β,γ-unsaturated imide followed by the siloxy-Cope rearrangement is shown to provide the γ,δ-anti- or -syn -α,β-unsaturated imide as the main product. Copyright (C) 1996 Elsevier Science Ltd.

Original language	English
Pages (from-to)	8899-8900
Number of pages	2
Journal	Tetrahedron Letters
Volume	37
Issue number	49
DOIs	https://doi.org/10.1016/S0040-4039(96)02078-3
Publication status	Published - Dec 2 1996
Externally published	Yes

All Science Journal Classification (ASJC) codes

Biochemistry
Drug Discovery
Organic Chemistry

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10.1016/S0040-4039(96)02078-3

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Chiral dienolate chemistry in remote asymmetric induction: The asymmetric aldol/oxy-Cope strategy for asymmetric synthesis of γ,δ-dichiral α,β-unsaturated acid derivatives. / Tomooka, Katsuhiko; Nagasawa, Atsushi; Wei, Shih Yi et al.
In: Tetrahedron Letters, Vol. 37, No. 49, 02.12.1996, p. 8899-8900.

Research output: Contribution to journal › Article › peer-review

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abstract = "The asymmetric aldol reaction of the boron dienolate derived from chiral α,β- or β,γ-unsaturated imide followed by the siloxy-Cope rearrangement is shown to provide the γ,δ-anti- or -syn -α,β-unsaturated imide as the main product. Copyright (C) 1996 Elsevier Science Ltd.",

author = "Katsuhiko Tomooka and Atsushi Nagasawa and Wei, {Shih Yi} and Takeshi Nakai",

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AU - Nakai, Takeshi

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Chiral dienolate chemistry in remote asymmetric induction: The asymmetric aldol/oxy-Cope strategy for asymmetric synthesis of γ,δ-dichiral α,β-unsaturated acid derivatives

Abstract

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