TY - JOUR
T1 - Chiral Interlocked Corrole Dimers Directly Linked at Inner Carbon Atoms of Confused Pyrrole Rings
AU - Kumar Maurya, Yogesh
AU - Wei, Pingchun
AU - Shimada, Takahide
AU - Yamasumi, Kazuhisa
AU - Mori, Shigeki
AU - Furukawa, Ko
AU - Kusaba, Hajime
AU - Ishihara, Tatsumi
AU - Xie, Yongshu
AU - Ishida, Masatoshi
AU - Furuta, Hiroyuki
N1 - Funding Information:
This work was supported by Grants-in-Aid (JP19K05439, JP19H04586, and JP20H00406) from the Japan Society for the Promotion of Science (JSPS).
Publisher Copyright:
© 2021 Wiley-VCH GmbH
PY - 2021/4/1
Y1 - 2021/4/1
N2 - A facile synthetic strategy towards conformationally stable chiral chromophores based on dimeric porphyrinoids has been established. A peculiar class of face-to-face intramolecularly interlocked corrole dimers were formed by the oxidative C−C coupling linked at the inner carbon sites upon simple treatment of copper(II) ions. Their intrinsic electronic structures were modulated by the peripheral corrole ring annulations, which lead to distinct optical properties and redox profiles. The stereogenic carbon centers implemented in the confused corrole skeleton provided a rationale for designing novel chiral materials.
AB - A facile synthetic strategy towards conformationally stable chiral chromophores based on dimeric porphyrinoids has been established. A peculiar class of face-to-face intramolecularly interlocked corrole dimers were formed by the oxidative C−C coupling linked at the inner carbon sites upon simple treatment of copper(II) ions. Their intrinsic electronic structures were modulated by the peripheral corrole ring annulations, which lead to distinct optical properties and redox profiles. The stereogenic carbon centers implemented in the confused corrole skeleton provided a rationale for designing novel chiral materials.
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U2 - 10.1002/asia.202100083
DO - 10.1002/asia.202100083
M3 - Article
C2 - 33624937
AN - SCOPUS:85102423045
SN - 1861-4728
VL - 16
SP - 743
EP - 747
JO - Chemistry - An Asian Journal
JF - Chemistry - An Asian Journal
IS - 7
ER -