Chiral (ON)Ru-salen catalyzed cyclopropanation: High cis- and enantio-selectivity

Tatsuya Uchida, Ryo Irie, Tsutomu Katsuki

Research output: Contribution to journalArticle

69 Citations (Scopus)

Abstract

(R,R)-(ON+)(Salen)ruthenium(II) complex 2 was found to be an effective catalyst for cis-selective asymmetric cyclopropanation (up to 89% ee) which was performed under sunlight coming through a window or incandescent light. Furthermore, (R,R)-(ON+)(hydroxo)-(salen)ruthenium(II) complex 5 was also found to show good cis- and enantio-selectivities (up to 92% ee) in the reaction in the dark.

Original languageEnglish
Pages (from-to)1163-1165
Number of pages3
JournalSynlett
Issue number7
DOIs
Publication statusPublished - Jan 1 1999

All Science Journal Classification (ASJC) codes

  • Organic Chemistry

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