TY - JOUR
T1 - Chirality transfer from epoxide to carbanion
T2 - Base-induced alkylation of O-carbamoyl cyanohydrins of β-silyl-α,β-epoxy aldehyde
AU - Sasaki, Michiko
AU - Kawanishi, Eiji
AU - Shirakawa, Yuri
AU - Kawahata, Masatoshi
AU - Masu, Hyuma
AU - Yamaguchi, Kentaro
AU - Takeda, Kei
PY - 2008/6/1
Y1 - 2008/6/1
N2 - Enantioselective C-C bond formation at an α-position of a nitrile group with an external electrophile can be realized, although in modest ee, with the aid of both the concerted process of an epoxysilane rearrangement and a carbamoyl group.
AB - Enantioselective C-C bond formation at an α-position of a nitrile group with an external electrophile can be realized, although in modest ee, with the aid of both the concerted process of an epoxysilane rearrangement and a carbamoyl group.
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U2 - 10.1002/ejoc.200800300
DO - 10.1002/ejoc.200800300
M3 - Article
AN - SCOPUS:53749100438
SN - 1434-193X
SP - 3061
EP - 3064
JO - Justus Liebigs Annalen der Chemie
JF - Justus Liebigs Annalen der Chemie
IS - 18
ER -