Chirally-ordered fullerene assemblies found in organic gel systems of cholesterol-appended [60]fullerenes

Tsutomu Ishi-i; Yoshiyuki Ono; Seiji Shinkai

doi:10.1246/cl.2000.808

Chirally-ordered fullerene assemblies found in organic gel systems of cholesterol-appended [60]fullerenes

Tsutomu Ishi-i, Yoshiyuki Ono, Seiji Shinkai

Research output: Contribution to journal › Article › peer-review

10 Citations (Scopus)

Abstract

Cholesterol-appended [60]fullerene gelators 2a and 2b were prepared and their gelation properties were investigated. 2a with a natural C-3 configuration can gelate dichloromethane whereas 2b with an inverted C-3 configuration could not gelate any solvents. UV/Vis and CD spectroscopic studies indicated that the [60]-fullerene moiety in 2a is enforced to chirally orient in the gel state.

Original language	English
Pages (from-to)	808-809
Number of pages	2
Journal	Chemistry Letters
Issue number	7
DOIs	https://doi.org/10.1246/cl.2000.808
Publication status	Published - 2000
Externally published	Yes

All Science Journal Classification (ASJC) codes

Chemistry(all)

Access to Document

10.1246/cl.2000.808

Cite this

@article{cbb0a5d43994479fa5d8be40314f6ed9,

title = "Chirally-ordered fullerene assemblies found in organic gel systems of cholesterol-appended [60]fullerenes",

abstract = "Cholesterol-appended [60]fullerene gelators 2a and 2b were prepared and their gelation properties were investigated. 2a with a natural C-3 configuration can gelate dichloromethane whereas 2b with an inverted C-3 configuration could not gelate any solvents. UV/Vis and CD spectroscopic studies indicated that the [60]-fullerene moiety in 2a is enforced to chirally orient in the gel state.",

author = "Tsutomu Ishi-i and Yoshiyuki Ono and Seiji Shinkai",

year = "2000",

doi = "10.1246/cl.2000.808",

language = "English",

pages = "808--809",

journal = "Chemistry Letters",

issn = "0366-7022",

publisher = "The Chemical Society of Japan",

number = "7",

}

TY - JOUR

T1 - Chirally-ordered fullerene assemblies found in organic gel systems of cholesterol-appended [60]fullerenes

AU - Ishi-i, Tsutomu

AU - Ono, Yoshiyuki

AU - Shinkai, Seiji

PY - 2000

Y1 - 2000

N2 - Cholesterol-appended [60]fullerene gelators 2a and 2b were prepared and their gelation properties were investigated. 2a with a natural C-3 configuration can gelate dichloromethane whereas 2b with an inverted C-3 configuration could not gelate any solvents. UV/Vis and CD spectroscopic studies indicated that the [60]-fullerene moiety in 2a is enforced to chirally orient in the gel state.

AB - Cholesterol-appended [60]fullerene gelators 2a and 2b were prepared and their gelation properties were investigated. 2a with a natural C-3 configuration can gelate dichloromethane whereas 2b with an inverted C-3 configuration could not gelate any solvents. UV/Vis and CD spectroscopic studies indicated that the [60]-fullerene moiety in 2a is enforced to chirally orient in the gel state.

UR - http://www.scopus.com/inward/record.url?scp=0034339595&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=0034339595&partnerID=8YFLogxK

U2 - 10.1246/cl.2000.808

DO - 10.1246/cl.2000.808

M3 - Article

AN - SCOPUS:0034339595

SN - 0366-7022

SP - 808

EP - 809

JO - Chemistry Letters

JF - Chemistry Letters

IS - 7

ER -

Chirally-ordered fullerene assemblies found in organic gel systems of cholesterol-appended [60]fullerenes

Abstract

All Science Journal Classification (ASJC) codes

Access to Document

Other files and links

Fingerprint

Cite this