Chiroselective re-binding of saccharides to the fibrous aggregates prepared from organic gels of cholesterylphenylboronic acid

Kazuhiko Inoue; Yoshiyuki Ono; Yasumasa Kanekiyo; Tsutomu Ishi-I; Kanami Yoshihara; Seiji Shinkai

doi:10.1016/S0040-4039(98)00435-3

Chiroselective re-binding of saccharides to the fibrous aggregates prepared from organic gels of cholesterylphenylboronic acid

Kazuhiko Inoue, Yoshiyuki Ono, Yasumasa Kanekiyo, Tsutomu Ishi-I, Kanami Yoshihara, Seiji Shinkai

Research output: Contribution to journal › Article › peer-review

31 Citations (Scopus)

Abstract

The xerogel fibers prepared from cholesterylphenylboronic acid or its D- or L-xylose complexes show the chiral discrimination ability in the re- binding of saccharides and partially retain the memory for the original imprinted saccharide. The novel findings indicate that the solgel phase transition in the organic gel is utilizable to the chiral discrimination and even to the molecular imprinting.

Original language	English
Pages (from-to)	2981-2984
Number of pages	4
Journal	Tetrahedron Letters
Volume	39
Issue number	19
DOIs	https://doi.org/10.1016/S0040-4039(98)00435-3
Publication status	Published - May 7 1998
Externally published	Yes

All Science Journal Classification (ASJC) codes

Biochemistry
Drug Discovery
Organic Chemistry

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10.1016/S0040-4039(98)00435-3

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Chiroselective re-binding of saccharides to the fibrous aggregates prepared from organic gels of cholesterylphenylboronic acid. / Inoue, Kazuhiko; Ono, Yoshiyuki; Kanekiyo, Yasumasa; Ishi-I, Tsutomu; Yoshihara, Kanami; Shinkai, Seiji.

In: Tetrahedron Letters, Vol. 39, No. 19, 07.05.1998, p. 2981-2984.

Research output: Contribution to journal › Article › peer-review

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AU - Inoue, Kazuhiko

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AU - Ishi-I, Tsutomu

AU - Yoshihara, Kanami

AU - Shinkai, Seiji

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AB - The xerogel fibers prepared from cholesterylphenylboronic acid or its D- or L-xylose complexes show the chiral discrimination ability in the re- binding of saccharides and partially retain the memory for the original imprinted saccharide. The novel findings indicate that the solgel phase transition in the organic gel is utilizable to the chiral discrimination and even to the molecular imprinting.

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Chiroselective re-binding of saccharides to the fibrous aggregates prepared from organic gels of cholesterylphenylboronic acid

Abstract

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