Chiroselective re-binding of saccharides to the fibrous aggregates prepared from organic gels of cholesterylphenylboronic acid

Kazuhiko Inoue, Yoshiyuki Ono, Yasumasa Kanekiyo, Tsutomu Ishi-I, Kanami Yoshihara, Seiji Shinkai

Research output: Contribution to journalArticle

30 Citations (Scopus)

Abstract

The xerogel fibers prepared from cholesterylphenylboronic acid or its D- or L-xylose complexes show the chiral discrimination ability in the re- binding of saccharides and partially retain the memory for the original imprinted saccharide. The novel findings indicate that the solgel phase transition in the organic gel is utilizable to the chiral discrimination and even to the molecular imprinting.

Original languageEnglish
Pages (from-to)2981-2984
Number of pages4
JournalTetrahedron Letters
Volume39
Issue number19
DOIs
Publication statusPublished - May 7 1998
Externally publishedYes

Fingerprint

Xerogels
Xylose
Molecular Imprinting
Phase transitions
Gels
Data storage equipment
Acids
Aptitude
Fibers
Phase Transition
Discrimination (Psychology)

All Science Journal Classification (ASJC) codes

  • Biochemistry
  • Drug Discovery
  • Organic Chemistry

Cite this

Chiroselective re-binding of saccharides to the fibrous aggregates prepared from organic gels of cholesterylphenylboronic acid. / Inoue, Kazuhiko; Ono, Yoshiyuki; Kanekiyo, Yasumasa; Ishi-I, Tsutomu; Yoshihara, Kanami; Shinkai, Seiji.

In: Tetrahedron Letters, Vol. 39, No. 19, 07.05.1998, p. 2981-2984.

Research output: Contribution to journalArticle

Inoue, Kazuhiko ; Ono, Yoshiyuki ; Kanekiyo, Yasumasa ; Ishi-I, Tsutomu ; Yoshihara, Kanami ; Shinkai, Seiji. / Chiroselective re-binding of saccharides to the fibrous aggregates prepared from organic gels of cholesterylphenylboronic acid. In: Tetrahedron Letters. 1998 ; Vol. 39, No. 19. pp. 2981-2984.
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