Chlorido(dimethyl sulfoxide-κS)[2-(2-pyrid-yl)phenyl- κ2 N,C 1]platinum(II)

Masayuki Kobayashi, Shigeyuki Masaoka, Ken Sakai

Research output: Contribution to journalArticle

7 Citations (Scopus)

Abstract

In the title compound, [Pt(C11H8N)Cl(C2H6OS)], the S atom of dimethyl sulfoxide is trans to the pyridyl N atom [Pt - S = 2.2181 (11) Å] and the chlorido ligand is trans to the carbon donor of 2-(2-pyrid-yl)phenyl [Pt - Cl = 2.4202 (10) Å]. The [2-(2-pyrid-yl)phen-yl]platinum(II) unit forms a one-dimensional stack along the c axis with two independent inter-planar separations of 3.44 (9) and 3.50 (2) Å.

Original languageEnglish
JournalActa Crystallographica Section E: Structure Reports Online
Volume64
Issue number10
DOIs
Publication statusPublished - Oct 13 2008

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Dimethyl sulfoxide
Dimethyl Sulfoxide
Platinum
platinum
Atoms
atoms
Carbon
Ligands
ligands
carbon

All Science Journal Classification (ASJC) codes

  • Chemistry(all)
  • Materials Science(all)
  • Condensed Matter Physics

Cite this

Chlorido(dimethyl sulfoxide-κS)[2-(2-pyrid-yl)phenyl- κ2 N,C 1]platinum(II). / Kobayashi, Masayuki; Masaoka, Shigeyuki; Sakai, Ken.

In: Acta Crystallographica Section E: Structure Reports Online, Vol. 64, No. 10, 13.10.2008.

Research output: Contribution to journalArticle

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AB - In the title compound, [Pt(C11H8N)Cl(C2H6OS)], the S atom of dimethyl sulfoxide is trans to the pyridyl N atom [Pt - S = 2.2181 (11) Å] and the chlorido ligand is trans to the carbon donor of 2-(2-pyrid-yl)phenyl [Pt - Cl = 2.4202 (10) Å]. The [2-(2-pyrid-yl)phen-yl]platinum(II) unit forms a one-dimensional stack along the c axis with two independent inter-planar separations of 3.44 (9) and 3.50 (2) Å.

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