Abstract
We investigated the addition of chromium to alumina-supported Pt catalysts and its effect on catalytic activity in methane combustion. The Pt and Cr binary alumina-supported catalysts exhibited much higher activity than those without Cr. Alumina-supported Cr catalysts contain two chromium species, Cr 3+ and Cr 6+. From XPS analysis, it was found that more Cr 6+ species existed in the binary catalysts than in the single alumina-supported Cr catalysts. Pt species in the binary catalysts may promote Cr oxidation. Since Cr 6+ species are known to be more active than Cr3ff species in oxidation reactions, the increase in Cr 6+ in the binary catalysts may contribute to their higher activity compared with the Pt/Al 2O 3 catalyst.
| Original language | English |
|---|---|
| Pages (from-to) | 493-497 |
| Number of pages | 5 |
| Journal | JOURNAL OF CHEMICAL ENGINEERING OF JAPAN |
| Volume | 45 |
| Issue number | 7 |
| DOIs | |
| Publication status | Published - Jul 31 2012 |
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All Science Journal Classification (ASJC) codes
- Chemistry(all)
- Chemical Engineering(all)
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Chromium addition to alumina-supported platinum catalysts and effect on catalytic activity in methane combustion. / Mardwita; Matsune, Hideki; Takenaka, Sakae; Kishida, Masahiro.
In: JOURNAL OF CHEMICAL ENGINEERING OF JAPAN, Vol. 45, No. 7, 31.07.2012, p. 493-497.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Chromium addition to alumina-supported platinum catalysts and effect on catalytic activity in methane combustion
AU - Mardwita,
AU - Matsune, Hideki
AU - Takenaka, Sakae
AU - Kishida, Masahiro
PY - 2012/7/31
Y1 - 2012/7/31
N2 - We investigated the addition of chromium to alumina-supported Pt catalysts and its effect on catalytic activity in methane combustion. The Pt and Cr binary alumina-supported catalysts exhibited much higher activity than those without Cr. Alumina-supported Cr catalysts contain two chromium species, Cr 3+ and Cr 6+. From XPS analysis, it was found that more Cr 6+ species existed in the binary catalysts than in the single alumina-supported Cr catalysts. Pt species in the binary catalysts may promote Cr oxidation. Since Cr 6+ species are known to be more active than Cr3ff species in oxidation reactions, the increase in Cr 6+ in the binary catalysts may contribute to their higher activity compared with the Pt/Al 2O 3 catalyst.
AB - We investigated the addition of chromium to alumina-supported Pt catalysts and its effect on catalytic activity in methane combustion. The Pt and Cr binary alumina-supported catalysts exhibited much higher activity than those without Cr. Alumina-supported Cr catalysts contain two chromium species, Cr 3+ and Cr 6+. From XPS analysis, it was found that more Cr 6+ species existed in the binary catalysts than in the single alumina-supported Cr catalysts. Pt species in the binary catalysts may promote Cr oxidation. Since Cr 6+ species are known to be more active than Cr3ff species in oxidation reactions, the increase in Cr 6+ in the binary catalysts may contribute to their higher activity compared with the Pt/Al 2O 3 catalyst.
UR - http://www.scopus.com/inward/record.url?scp=84864319986&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=84864319986&partnerID=8YFLogxK
U2 - 10.1252/jcej.12we025
DO - 10.1252/jcej.12we025
M3 - Article
AN - SCOPUS:84864319986
VL - 45
SP - 493
EP - 497
JO - Journal of Chemical Engineering of Japan
JF - Journal of Chemical Engineering of Japan
SN - 0021-9592
IS - 7
ER -