cis-Dichlorobis(4-methylpyridine-κN)platinum(II)

Ken Sakai; Yuki Yokoyama; Shigeyuki Masaoka

doi:10.1107/S1600536806051610

cis-Dichlorobis(4-methylpyridine-κN)platinum(II)

Ken Sakai, Yuki Yokoyama, Shigeyuki Masaoka

Inorganic and Analytical Chemistry

Research output: Contribution to journal › Article › peer-review

6 Citations (Scopus)

Abstract

In the title molecule, cis-[PtCl₂(C₆H ₇N)₂], the Ft^II coordination plane has a distorted structure in which the cis-PtCl₂ unit is tilted by 4.3 (2)° with respect to the cis-PtN₂ unit. The two pyridyl planes are inclined at angles of 64.8 (1) and 77.5 (2)° with respect to the cis-PtN₂ unit, which is partly interpreted in terms of the intermolecular C-H(methyl)⋯π(pyridine) interactions in the crystal structure.

Original language	English
Pages (from-to)	m97-m99
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	63
Issue number	1
DOIs	https://doi.org/10.1107/S1600536806051610
Publication status	Published - Jan 2007

All Science Journal Classification (ASJC) codes

Chemistry(all)
Materials Science(all)
Condensed Matter Physics

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title = "cis-Dichlorobis(4-methylpyridine-κN)platinum(II)",

abstract = "In the title molecule, cis-[PtCl2(C6H 7N)2], the FtII coordination plane has a distorted structure in which the cis-PtCl2 unit is tilted by 4.3 (2)° with respect to the cis-PtN2 unit. The two pyridyl planes are inclined at angles of 64.8 (1) and 77.5 (2)° with respect to the cis-PtN2 unit, which is partly interpreted in terms of the intermolecular C-H(methyl)⋯π(pyridine) interactions in the crystal structure.",

author = "Ken Sakai and Yuki Yokoyama and Shigeyuki Masaoka",

year = "2007",

month = jan,

doi = "10.1107/S1600536806051610",

language = "English",

volume = "63",

pages = "m97--m99",

journal = "Acta Crystallographica Section E: Structure Reports Online",

issn = "1600-5368",

publisher = "International Union of Crystallography",

number = "1",

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TY - JOUR

T1 - cis-Dichlorobis(4-methylpyridine-κN)platinum(II)

AU - Sakai, Ken

AU - Yokoyama, Yuki

AU - Masaoka, Shigeyuki

PY - 2007/1

Y1 - 2007/1

N2 - In the title molecule, cis-[PtCl2(C6H 7N)2], the FtII coordination plane has a distorted structure in which the cis-PtCl2 unit is tilted by 4.3 (2)° with respect to the cis-PtN2 unit. The two pyridyl planes are inclined at angles of 64.8 (1) and 77.5 (2)° with respect to the cis-PtN2 unit, which is partly interpreted in terms of the intermolecular C-H(methyl)⋯π(pyridine) interactions in the crystal structure.

AB - In the title molecule, cis-[PtCl2(C6H 7N)2], the FtII coordination plane has a distorted structure in which the cis-PtCl2 unit is tilted by 4.3 (2)° with respect to the cis-PtN2 unit. The two pyridyl planes are inclined at angles of 64.8 (1) and 77.5 (2)° with respect to the cis-PtN2 unit, which is partly interpreted in terms of the intermolecular C-H(methyl)⋯π(pyridine) interactions in the crystal structure.

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SP - m97-m99

JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

IS - 1

ER -

cis-Dichlorobis(4-methylpyridine-κN)platinum(II)

Abstract

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