Cluster-Based Haldane State in an Edge-Shared Tetrahedral Spin-Cluster Chain: Fedotovite K2Cu3 O (SO4)3

M. Fujihala, T. Sugimoto, T. Tohyama, S. Mitsuda, R. A. Mole, D. H. Yu, S. Yano, Y. Inagaki, H. Morodomi, T. Kawae, H. Sagayama, R. Kumai, Y. Murakami, K. Tomiyasu, A. Matsuo, K. Kindo

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Abstract

Fedotovite K2Cu3O(SO4)3 is a candidate of new quantum spin systems, in which the edge-shared tetrahedral (EST) spin clusters consisting of Cu2+ are connected by weak intercluster couplings forming a one-dimensional array. Comprehensive experimental studies by magnetic susceptibility, magnetization, heat capacity, and inelastic neutron scattering measurements reveal the presence of an effective S=1 Haldane state below T≅4 K. Rigorous theoretical studies provide an insight into the magnetic state of K2Cu3O(SO4)3: an EST cluster makes a triplet in the ground state and a one-dimensional chain of the EST induces a cluster-based Haldane state. We predict that the cluster-based Haldane state emerges whenever the number of tetrahedra in the EST is even.

Original languageEnglish
Article number077201
JournalPhysical Review Letters
Volume120
Issue number7
DOIs
Publication statusPublished - Feb 12 2018

All Science Journal Classification (ASJC) codes

  • Physics and Astronomy(all)

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    Fujihala, M., Sugimoto, T., Tohyama, T., Mitsuda, S., Mole, R. A., Yu, D. H., Yano, S., Inagaki, Y., Morodomi, H., Kawae, T., Sagayama, H., Kumai, R., Murakami, Y., Tomiyasu, K., Matsuo, A., & Kindo, K. (2018). Cluster-Based Haldane State in an Edge-Shared Tetrahedral Spin-Cluster Chain: Fedotovite K2Cu3 O (SO4)3. Physical Review Letters, 120(7), [077201]. https://doi.org/10.1103/PhysRevLett.120.077201