Coating of 2D flexible metalorganic frameworks on metal nanocrystals

Naoki Ogiwara, Hirokazu Kobayashi, Keigo Kobayashi, Tomokazu Yamamoto, Takaaki Toriyama, Syo Matsumura, Hiroshi Kitagawa

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Abstract

We report, for the first time, metal (Pd) nanocrystals (NCs) covered with a 2D flexible metalorganic framework (MOF) of [Zn(NO2-ip)(bpy)]n (NO2-ip: 5-nitro-isophthalate, bpy: 4,4¤-bipyridine). The hybrid materials were characterized by powder X-ray diffraction measurements and transmission electron microscope techniques. The CO2 sorption and hydrogen storage properties revealed that both the flexible porous character of the MOF and the hydrogen absorption ability of Pd NCs were compatible in the hybrid.

Original languageEnglish
Pages (from-to)173-176
Number of pages4
JournalChemistry Letters
Volume48
Issue number2
DOIs
Publication statusPublished - Jan 1 2019

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All Science Journal Classification (ASJC) codes

  • Chemistry(all)

Cite this

Ogiwara, N., Kobayashi, H., Kobayashi, K., Yamamoto, T., Toriyama, T., Matsumura, S., & Kitagawa, H. (2019). Coating of 2D flexible metalorganic frameworks on metal nanocrystals. Chemistry Letters, 48(2), 173-176. https://doi.org/10.1246/cl.180931