Coating of 2D flexible metalorganic frameworks on metal nanocrystals

Naoki Ogiwara; Hirokazu Kobayashi; Keigo Kobayashi; Tomokazu Yamamoto; Takaaki Toriyama; Syo Matsumura; Hiroshi Kitagawa

doi:10.1246/cl.180931

Coating of 2D flexible metalorganic frameworks on metal nanocrystals

Naoki Ogiwara, Hirokazu Kobayashi, Keigo Kobayashi, Tomokazu Yamamoto, Takaaki Toriyama, Syo Matsumura, Hiroshi Kitagawa

Research output: Contribution to journal › Article › peer-review

3 Citations (Scopus)

Abstract

We report, for the first time, metal (Pd) nanocrystals (NCs) covered with a 2D flexible metalorganic framework (MOF) of [Zn(NO₂-ip)(bpy)]_n (NO₂-ip: 5-nitro-isophthalate, bpy: 4,4¤-bipyridine). The hybrid materials were characterized by powder X-ray diffraction measurements and transmission electron microscope techniques. The CO₂ sorption and hydrogen storage properties revealed that both the flexible porous character of the MOF and the hydrogen absorption ability of Pd NCs were compatible in the hybrid.

Original language	English
Pages (from-to)	173-176
Number of pages	4
Journal	Chemistry Letters
Volume	48
Issue number	2
DOIs	https://doi.org/10.1246/cl.180931
Publication status	Published - 2019

All Science Journal Classification (ASJC) codes

Chemistry(all)

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title = "Coating of 2D flexible metalorganic frameworks on metal nanocrystals",

abstract = "We report, for the first time, metal (Pd) nanocrystals (NCs) covered with a 2D flexible metalorganic framework (MOF) of [Zn(NO2-ip)(bpy)]n (NO2-ip: 5-nitro-isophthalate, bpy: 4,4¤-bipyridine). The hybrid materials were characterized by powder X-ray diffraction measurements and transmission electron microscope techniques. The CO2 sorption and hydrogen storage properties revealed that both the flexible porous character of the MOF and the hydrogen absorption ability of Pd NCs were compatible in the hybrid.",

author = "Naoki Ogiwara and Hirokazu Kobayashi and Keigo Kobayashi and Tomokazu Yamamoto and Takaaki Toriyama and Syo Matsumura and Hiroshi Kitagawa",

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journal = "Chemistry Letters",

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T1 - Coating of 2D flexible metalorganic frameworks on metal nanocrystals

AU - Ogiwara, Naoki

AU - Kobayashi, Hirokazu

AU - Kobayashi, Keigo

AU - Yamamoto, Tomokazu

AU - Toriyama, Takaaki

AU - Matsumura, Syo

AU - Kitagawa, Hiroshi

PY - 2019

Y1 - 2019

N2 - We report, for the first time, metal (Pd) nanocrystals (NCs) covered with a 2D flexible metalorganic framework (MOF) of [Zn(NO2-ip)(bpy)]n (NO2-ip: 5-nitro-isophthalate, bpy: 4,4¤-bipyridine). The hybrid materials were characterized by powder X-ray diffraction measurements and transmission electron microscope techniques. The CO2 sorption and hydrogen storage properties revealed that both the flexible porous character of the MOF and the hydrogen absorption ability of Pd NCs were compatible in the hybrid.

AB - We report, for the first time, metal (Pd) nanocrystals (NCs) covered with a 2D flexible metalorganic framework (MOF) of [Zn(NO2-ip)(bpy)]n (NO2-ip: 5-nitro-isophthalate, bpy: 4,4¤-bipyridine). The hybrid materials were characterized by powder X-ray diffraction measurements and transmission electron microscope techniques. The CO2 sorption and hydrogen storage properties revealed that both the flexible porous character of the MOF and the hydrogen absorption ability of Pd NCs were compatible in the hybrid.

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SP - 173

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JO - Chemistry Letters

JF - Chemistry Letters

IS - 2

ER -

Coating of 2D flexible metalorganic frameworks on metal nanocrystals

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