Codeposition behavior of impurity during electrogalvanizing in sulfate bath in the presence of Fe ions

Hiroaki Nakano, Satoshi Oue, Shoji Hisano, Shigeo Kobayashi, Hisaaki Fukushima

Research output: Contribution to journalArticle

Abstract

The codeposition behavior of impurity Fe with Zn was investigated galvanostatically over the current density range from 1 to 1000 A/m2 at 40°C in zinc sulfate solution of pH 3 containing 5000 ppm of Fe 2 and the other organic or inorganic impurity. Fe hardly codeposited with Zn in the solution containing both Fe and Mo or Ni as impurity. The codeposition of Fe seems to be strongly suppressed in the presence of Zn 2+ ions due to the adsorption of Zn hydroxide preferentially formed on the cathode. However, in the solution containing Fe and Cu, Fe evidently codeposited with Zn. The Fe content in deposit decreased with increasing the current density. The role of codeposited Cu is considered to promote Fe deposition by providing an active sites free from adsorbed Zn hydroxide. On the other hand, in the solution containing Fe and stearyle benzyl ammonium chloride (CIS-Benzyl) as impurities, the eodeposition of Fe was significantly recognized. The cathode potential for Zn deposition was greatly polarized by addition of C18-Benzyl and the Fe content in deposit increased with increasing the current density.

Original languageEnglish
Pages (from-to)39-43
Number of pages5
JournalTetsu-To-Hagane/Journal of the Iron and Steel Institute of Japan
Volume93
Issue number1
DOIs
Publication statusPublished - Jan 1 2007

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Sulfates
baths
sulfates
Impurities
Ions
impurities
Current density
current density
hydroxides
ions
Cathodes
Deposits
cathodes
deposits
Zinc Sulfate
Ammonium Chloride
Commonwealth of Independent States
ammonium chlorides
Zinc
zinc

All Science Journal Classification (ASJC) codes

  • Condensed Matter Physics
  • Physical and Theoretical Chemistry
  • Metals and Alloys
  • Materials Chemistry

Cite this

Codeposition behavior of impurity during electrogalvanizing in sulfate bath in the presence of Fe ions. / Nakano, Hiroaki; Oue, Satoshi; Hisano, Shoji; Kobayashi, Shigeo; Fukushima, Hisaaki.

In: Tetsu-To-Hagane/Journal of the Iron and Steel Institute of Japan, Vol. 93, No. 1, 01.01.2007, p. 39-43.

Research output: Contribution to journalArticle

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