Combined in Situ XAFS and FTIR Study of the Hydrodeoxygenation Reaction of 2-Methyltetrahydrofuran on Ni 2 P/SiO 2

Ayako Iino, Atsushi Takagaki, Ryuji Kikuchi, S. Ted Oyama, Kyoko K. Bando

Research output: Contribution to journalArticle

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Abstract

This paper deals with a study of the mechanism of hydrodeoxygenation (HDO) at 0.1 MPa and 300-350 °C of 2-methyltetrahydrofuran (2-MTHF) over a Ni 2 P/SiO 2 catalyst. The study was conducted using in situ Fourier transform infrared (FTIR) spectroscopy to monitor the adsorbed species during reaction and in situ X-ray absorption fine structure (XAFS) to probe the oxidation state of the Ni component. The work is relevant to the upgrading of bio-oil derived from the pyrolysis of biomass. It was deduced that the initial interaction of the 2-MTHF was with OH groups on the catalyst surface, followed by adsorption on Ni sites. Ring-opening of the tetrahydrofuran led to the formation of the main products of the reaction, n-pentane by HDO and n-butane + CO by decarbonylation. The CO band appeared with a slight delay in the FTIR spectrum because the reaction to form n-pentane was favored and turned over about four times before one n-butane + CO was formed.

Original languageEnglish
Pages (from-to)7633-7643
Number of pages11
JournalJournal of Physical Chemistry C
Volume123
Issue number13
DOIs
Publication statusPublished - Apr 4 2019

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X ray absorption
Butane
Carbon Monoxide
Fourier transforms
fine structure
pentanes
butanes
Infrared radiation
Catalysts
Fourier transform infrared spectroscopy
catalysts
Biomass
Pyrolysis
x rays
upgrading
biomass
tetrahydrofuran
Adsorption
Oxidation
pyrolysis

All Science Journal Classification (ASJC) codes

  • Electronic, Optical and Magnetic Materials
  • Energy(all)
  • Physical and Theoretical Chemistry
  • Surfaces, Coatings and Films

Cite this

Combined in Situ XAFS and FTIR Study of the Hydrodeoxygenation Reaction of 2-Methyltetrahydrofuran on Ni 2 P/SiO 2 . / Iino, Ayako; Takagaki, Atsushi; Kikuchi, Ryuji; Oyama, S. Ted; Bando, Kyoko K.

In: Journal of Physical Chemistry C, Vol. 123, No. 13, 04.04.2019, p. 7633-7643.

Research output: Contribution to journalArticle

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