Comparative study of propane steam reforming in vanadium based catalytic membrane reactor with nickel-based catalysts

Maki Matsuka, Kazuki Shigedomi, Tatsumi Ishihara

Research output: Contribution to journalArticle

14 Citations (Scopus)

Abstract

The performance of catalytic membrane reactor with Pd-coated V membrane was examined for steam reforming of propane. The long term reforming experiment confirmed the stability of the V membrane with high hydrogen selectivity and permeability. The effect of types of hydrogen permeable membranes on the performance of the catalytic membrane reactor was studied by comparing Pd-coated V, Pd-23Ag, and Pd-10Ag membranes. The types of hydrogen separation membranes (i.e. hydrogen removal rates) did not have a marked effect on the propane conversion rates, while the product compositions were largely influenced by the hydrogen removal rate. Varying metal oxide supports of Ni-catalysts resulted in significant differences in the product compositions. Further, the evaluation of various catalyst-support systems (9wt%Ni-1wt%M/CeO2, M = Co, Pt, Ag, Ru) revealed that hydrogen yield was the highest when 1wt%Ag was added to Ni/CeO2. However, it was also found that excessive secondary metal additions can have negative impact on the catalytic behaviour of parent catalysts.

Original languageEnglish
Pages (from-to)14792-14799
Number of pages8
JournalInternational Journal of Hydrogen Energy
Volume39
Issue number27
DOIs
Publication statusPublished - Sep 12 2014

Fingerprint

Steam reforming
Propane
propane
steam
Vanadium
vanadium
reactors
Nickel
nickel
membranes
Membranes
catalysts
Catalysts
Hydrogen
hydrogen
Catalyst supports
support systems
products
Reforming reactions
Metals

All Science Journal Classification (ASJC) codes

  • Renewable Energy, Sustainability and the Environment
  • Fuel Technology
  • Condensed Matter Physics
  • Energy Engineering and Power Technology

Cite this

Comparative study of propane steam reforming in vanadium based catalytic membrane reactor with nickel-based catalysts. / Matsuka, Maki; Shigedomi, Kazuki; Ishihara, Tatsumi.

In: International Journal of Hydrogen Energy, Vol. 39, No. 27, 12.09.2014, p. 14792-14799.

Research output: Contribution to journalArticle

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