Competing Structural Instabilities in the Ruddlesden-Popper Derivatives HRTiO4 (R = Rare Earths)

Oxygen Octahedral Rotations Inducing Noncentrosymmetricity and Layer Sliding Retaining Centrosymmetricity

Arnab Sen Gupta, Hirofumi Akamatsu, Forrest G. Brown, Minh An T. Nguyen, Megan E. Strayer, Saul Lapidus, Suguru Yoshida, Koji Fujita, Katsuhisa Tanaka, Isao Tanaka, Thomas E. Mallouk, Venkatraman Gopalan

Research output: Contribution to journalArticle

7 Citations (Scopus)

Abstract

We report the observation of noncentrosymmetricity in the family of HRTiO4 (R = Eu, Gd, Dy) layered oxides possessing a Ruddlesden-Popper derivative structure, by second harmonic generation and synchrotron X-ray diffraction with the support of density functional theory calculations. These oxides were previously thought to possess inversion symmetry. Here, inversion symmetry is lifted by rotations of the oxygen-coordinated octahedra, a mechanism that is not active in simple perovskites. We observe a competition between rotations of the oxygen octahedra and sliding of a combined unit of perovskite-rocksalt-perovskite blocks at the proton layers. For the smaller rare earth ions, R = Eu, Gd, and Dy, which favor the octahedral rotations, noncentrosymmetricity is present but the sliding is absent. For the larger rare earth ions, R = Nd and Sm, the octahedral rotations are absent, but the sliding at the proton layers is present to optimize the length and direction of hydrogen bonding in the crystal structure. The study reveals a new mechanism for inducing noncentrosymmetricity in layered oxides, and chemical-structural effects related to rare earth ion size and hydrogen bonding that can turn this mechanism on and off. We construct a phase diagram of temperature versus rare earth ionic radius for the HRTiO4 family.

Original languageEnglish
Pages (from-to)656-665
Number of pages10
JournalChemistry of Materials
Volume29
Issue number2
DOIs
Publication statusPublished - Jan 24 2017
Externally publishedYes

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Rare earths
Oxides
Oxygen
Derivatives
Ions
Perovskite
Protons
Hydrogen bonds
Harmonic generation
Synchrotrons
Phase diagrams
Density functional theory
Crystal structure
X ray diffraction
Temperature
perovskite

All Science Journal Classification (ASJC) codes

  • Chemistry(all)
  • Chemical Engineering(all)
  • Materials Chemistry

Cite this

Competing Structural Instabilities in the Ruddlesden-Popper Derivatives HRTiO4 (R = Rare Earths) : Oxygen Octahedral Rotations Inducing Noncentrosymmetricity and Layer Sliding Retaining Centrosymmetricity. / Sen Gupta, Arnab; Akamatsu, Hirofumi; Brown, Forrest G.; Nguyen, Minh An T.; Strayer, Megan E.; Lapidus, Saul; Yoshida, Suguru; Fujita, Koji; Tanaka, Katsuhisa; Tanaka, Isao; Mallouk, Thomas E.; Gopalan, Venkatraman.

In: Chemistry of Materials, Vol. 29, No. 2, 24.01.2017, p. 656-665.

Research output: Contribution to journalArticle

Sen Gupta, Arnab ; Akamatsu, Hirofumi ; Brown, Forrest G. ; Nguyen, Minh An T. ; Strayer, Megan E. ; Lapidus, Saul ; Yoshida, Suguru ; Fujita, Koji ; Tanaka, Katsuhisa ; Tanaka, Isao ; Mallouk, Thomas E. ; Gopalan, Venkatraman. / Competing Structural Instabilities in the Ruddlesden-Popper Derivatives HRTiO4 (R = Rare Earths) : Oxygen Octahedral Rotations Inducing Noncentrosymmetricity and Layer Sliding Retaining Centrosymmetricity. In: Chemistry of Materials. 2017 ; Vol. 29, No. 2. pp. 656-665.
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AU - Sen Gupta, Arnab

AU - Akamatsu, Hirofumi

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AB - We report the observation of noncentrosymmetricity in the family of HRTiO4 (R = Eu, Gd, Dy) layered oxides possessing a Ruddlesden-Popper derivative structure, by second harmonic generation and synchrotron X-ray diffraction with the support of density functional theory calculations. These oxides were previously thought to possess inversion symmetry. Here, inversion symmetry is lifted by rotations of the oxygen-coordinated octahedra, a mechanism that is not active in simple perovskites. We observe a competition between rotations of the oxygen octahedra and sliding of a combined unit of perovskite-rocksalt-perovskite blocks at the proton layers. For the smaller rare earth ions, R = Eu, Gd, and Dy, which favor the octahedral rotations, noncentrosymmetricity is present but the sliding is absent. For the larger rare earth ions, R = Nd and Sm, the octahedral rotations are absent, but the sliding at the proton layers is present to optimize the length and direction of hydrogen bonding in the crystal structure. The study reveals a new mechanism for inducing noncentrosymmetricity in layered oxides, and chemical-structural effects related to rare earth ion size and hydrogen bonding that can turn this mechanism on and off. We construct a phase diagram of temperature versus rare earth ionic radius for the HRTiO4 family.

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