Completely fused diporphyrins and tripophyrin

Akihiko Tsuda, Hiroyuki Furuta, Atsuhiro Osuka

Research output: Contribution to journalArticlepeer-review

174 Citations (Scopus)

Abstract

Extremely delocalized π-electronic systems are found in triply linked, fused porphyrins, which are formed by the oxidation of diporphyrins [Eq. (1)]. Stronger electronic interaction is observed in the triply linked diporphyrins, as evidenced by intensified and red-shifted Q bands and by lower one-electron oxidation potentials, as a consequence of their greater planarity. Hence they should have applications as electronic wires.

Original languageEnglish
Pages (from-to)2549-2552
Number of pages4
JournalAngewandte Chemie - International Edition
Volume39
Issue number14
DOIs
Publication statusPublished - Jul 17 2000
Externally publishedYes

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Chemistry(all)

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