Completely stereospecific 1,2-migration of alkyl groups in Et2AlCl promoted pinacol-type rearrangement

Gen ichi Tsuchihashi, Katsuhiko Tomooka, Keisuke Suzuki

Research output: Contribution to journalArticle

32 Citations (Scopus)

Abstract

Completely stereospecific 1,2-migration of alkyl groups was achieved in Et2AlCl promoted pinacol-type rearrangement of chiral β-mesyloxy alcohols to give optically pure α-alkyl ketones including both enantiomers of 4-methyl-3-hexanone, an alarm pheromone of ant.

Original languageEnglish
Pages (from-to)4253-4256
Number of pages4
JournalTetrahedron Letters
Volume25
Issue number38
DOIs
Publication statusPublished - Jan 1 1984

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Hexanones
Ants
Enantiomers
Pheromones
Ketones
Alcohols

All Science Journal Classification (ASJC) codes

  • Biochemistry
  • Drug Discovery
  • Organic Chemistry

Cite this

Completely stereospecific 1,2-migration of alkyl groups in Et2AlCl promoted pinacol-type rearrangement. / Tsuchihashi, Gen ichi; Tomooka, Katsuhiko; Suzuki, Keisuke.

In: Tetrahedron Letters, Vol. 25, No. 38, 01.01.1984, p. 4253-4256.

Research output: Contribution to journalArticle

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