Complexation behaviors of polyether-type fluorescent reagents having anthracene units at their terminals

Takahisa Anada, Takuya Kitaoka, Hideyuki Ota, Yusuke Kakizawa, Takahiro Akita, Tatsuya Morozumi, Hiroshi Nakamura

Research output: Contribution to journalArticle

5 Citations (Scopus)

Abstract

A new fluorescent reagent, N,N'-(4,7,10-trioxatridecane-1, 13-diyl)bis(anthracene-9-carbonamide) (5), and its analogues(1-4 and 6), which have two anthracene moieties at both terminals of linear polyethers, were synthesized. Their complexation behavior with alkaline earth cations was investigated by fluorescence spectrometry, fluorescence life- time, and 1H NMR spectrometry. When metal ions were added to these reagent solutions, fluorescence spectral changes were observed. In particular, 5 showed a drastic change in the fluorescence spectra accompanied by metal ion binding. The fluorescence spectra of 5 completely changed from that of monomer to excimer emission. All reagents formed a 1 : 1 complex with alkaline earth cations. The 1H NMR spectra of 5 with alkaline earth cations suggested the stacking of two anthracene moieties with each other. However, the interactions between two anthracenes were weak on the ground state for the other compounds (1 - 4 and 6).

Original languageEnglish
Pages (from-to)1107-1114
Number of pages8
Journalbunseki kagaku
Volume48
Issue number12
DOIs
Publication statusPublished - Jan 1 1999
Externally publishedYes

All Science Journal Classification (ASJC) codes

  • Analytical Chemistry

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