Concerted catalysis by nanocellulose and proline in organocatalytic Michael additions

Naliharifetra Jessica Ranaivoarimanana, Kyohei Kanomata, Takuya Kitaoka

Research output: Contribution to journalArticlepeer-review

5 Citations (Scopus)

Abstract

Cellulose nanofibers (CNFs) have recently attracted much attention as catalysts in various reactions. Organocatalysts have emerged as sustainable alternatives to metal-based catalysts in green organic synthesis, with concerted systems containing CNFs that are expected to provide next-generation catalysis. Herein, for the first time, we report that a representative organocatalyst comprising an unexpected combination of 2,2,6,6-tetramethylpiperidine 1-oxyl (TEMPO)-oxidized CNFs and proline shows significantly enhanced catalytic activity in an asymmetric Michael addition.

Original languageEnglish
Article number1231
JournalMolecules
Volume24
Issue number7
DOIs
Publication statusPublished - Mar 29 2019

All Science Journal Classification (ASJC) codes

  • Analytical Chemistry
  • Chemistry (miscellaneous)
  • Molecular Medicine
  • Pharmaceutical Science
  • Drug Discovery
  • Physical and Theoretical Chemistry
  • Organic Chemistry

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