Concerto catalysis - Harmonising [NiFe]hydrogenase and NiRu model catalysts

Koji Ichikawa; Kyoshiro Nonaka; Takahiro Matsumoto; Bunsho Kure; Ki Seok Yoon; Yoshiki Higuchi; Tatsuhiko Yagi; Seiji Ogo

doi:10.1039/b926061g

Concerto catalysis - Harmonising [NiFe]hydrogenase and NiRu model catalysts

Koji Ichikawa, Kyoshiro Nonaka, Takahiro Matsumoto, Bunsho Kure, Ki Seok Yoon, Yoshiki Higuchi, Tatsuhiko Yagi, Seiji Ogo

Research output: Contribution to journal › Article

10 Citations (Scopus)

Abstract

This communication reports the successful merging of the chemical properties of a natural [NiFe]hydrogenase (Desulfovibrio vulgaris Miyazaki F) and our previously reported [NiRu] hydrogenase-mimic. The catalytic activity of both the natural enzyme and the mimic is almost identical, with the exception of working pH ranges, and this allows us to use them simultaneously in the same reaction flask. In such a manner, isotope exchange between D₂ and H₂O could be conducted over an extended pH range (about 2-10) in one pot under mild conditions at ambient temperature and pressure.

Original language	English
Pages (from-to)	2993-2994
Number of pages	2
Journal	Dalton Transactions
Volume	39
Issue number	12
DOIs	https://doi.org/10.1039/b926061g
Publication status	Published - 2010

All Science Journal Classification (ASJC) codes

Inorganic Chemistry

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10.1039/b926061g

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Ichikawa, K., Nonaka, K., Matsumoto, T., Kure, B., Yoon, K. S., Higuchi, Y., Yagi, T., & Ogo, S. (2010). Concerto catalysis - Harmonising [NiFe]hydrogenase and NiRu model catalysts. Dalton Transactions, 39(12), 2993-2994. https://doi.org/10.1039/b926061g

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AU - Yoon, Ki Seok

AU - Higuchi, Yoshiki

AU - Yagi, Tatsuhiko

AU - Ogo, Seiji

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