Confinement Effect on the Effective Viscosity of Plasticized Polymer Films

F. Chen, D. Peng, Y. Ogata, K. Tanaka, Z. Yang, Y. Fujii, N. L. Yamada, C. H. Lam, O. K.C. Tsui

    Research output: Contribution to journalArticlepeer-review

    19 Citations (Scopus)

    Abstract

    We have measured the effective viscosity of polystyrene films with a small (4 wt %) added amount of dioctyl phthalate (DOP) deposited on silica. A broad range of molecular weights, Mw, from 13.7 to 2100 kg/mol was investigated. Our result shows that for the thin films with Mw < ∼100 kg/mol the addition of DOP causes the effective viscosity to decrease by a factor of ∼4, independent of Mw. But for the higher Mw films, the effective viscosity of the DOP added films creeps toward that of the neat films with increasing Mw. A model assuming the effective viscosity to be dominated by enhanced surface mobility for the lower Mw films but surface-promoted interfacial slippage for the higher Mw films is able to account for the experimental observations.

    Original languageEnglish
    Pages (from-to)7719-7726
    Number of pages8
    JournalMacromolecules
    Volume48
    Issue number20
    DOIs
    Publication statusPublished - Oct 27 2015

    All Science Journal Classification (ASJC) codes

    • Organic Chemistry
    • Polymers and Plastics
    • Inorganic Chemistry
    • Materials Chemistry

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