Construction of an aryliridium-salen complex for highly cis- and enantioselective cyclopropanations

Shigefumi Kanchiku, Hidehiro Suematsu, Kazuhiro Matsumoto, Tatsuya Uchida, Tsutomu Katsuki

Research output: Contribution to journalArticle

51 Citations (Scopus)

Abstract

(Chemical Equation Presented) Ringing the changes: Iridium(lll)-salen complexes 1 bearing a σ-coordinated aryl ligand (L = CH3C 6H4, C6H5) at the apical position are found to efficiently catalyze the cis- and enantioselective cyclopropanation of mono- and disubstituted olefins (see scheme).

Original languageEnglish
Pages (from-to)3889-3891
Number of pages3
JournalAngewandte Chemie - International Edition
Volume46
Issue number21
DOIs
Publication statusPublished - Jun 27 2007

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Bearings (structural)
Iridium
Alkenes
Olefins
Ligands
disalicylaldehyde ethylenediamine

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Chemistry(all)

Cite this

Construction of an aryliridium-salen complex for highly cis- and enantioselective cyclopropanations. / Kanchiku, Shigefumi; Suematsu, Hidehiro; Matsumoto, Kazuhiro; Uchida, Tatsuya; Katsuki, Tsutomu.

In: Angewandte Chemie - International Edition, Vol. 46, No. 21, 27.06.2007, p. 3889-3891.

Research output: Contribution to journalArticle

Kanchiku, Shigefumi ; Suematsu, Hidehiro ; Matsumoto, Kazuhiro ; Uchida, Tatsuya ; Katsuki, Tsutomu. / Construction of an aryliridium-salen complex for highly cis- and enantioselective cyclopropanations. In: Angewandte Chemie - International Edition. 2007 ; Vol. 46, No. 21. pp. 3889-3891.
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