Controlling stacking order and charge transport in π-stacks of aromatic molecules based on surface assembly

Madoka Iwane; Tomofumi Tada; Takafumi Osuga; Takashi Murase; Makoto Fujita; Tomoaki Nishino; Manabu Kiguchi; Shintaro Fujii

doi:10.1039/c8cc06430j

Controlling stacking order and charge transport in π-stacks of aromatic molecules based on surface assembly

Madoka Iwane, Tomofumi Tada, Takafumi Osuga, Takashi Murase, Makoto Fujita, Tomoaki Nishino, Manabu Kiguchi, Shintaro Fujii

Research output: Contribution to journal › Article › peer-review

14 Citations (Scopus)

Abstract

Here, we report a facile procedure based on surface self-assembly for controlling the π-π stacking order and relevant rectified charge transport properties in stacks of aromatic molecules on a single-molecule scale. A high rectification ratio of 10 was achieved and the rectification direction was uniquely determined by the controlled stacking order of the aromatic molecules on the graphene layers of HOPG.

Original language	English
Pages (from-to)	12443-12446
Number of pages	4
Journal	Chemical Communications
Volume	54
Issue number	88
DOIs	https://doi.org/10.1039/c8cc06430j
Publication status	Published - 2018
Externally published	Yes

All Science Journal Classification (ASJC) codes

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
Chemistry(all)
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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10.1039/c8cc06430j

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abstract = "Here, we report a facile procedure based on surface self-assembly for controlling the π-π stacking order and relevant rectified charge transport properties in stacks of aromatic molecules on a single-molecule scale. A high rectification ratio of 10 was achieved and the rectification direction was uniquely determined by the controlled stacking order of the aromatic molecules on the graphene layers of HOPG.",

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AU - Iwane, Madoka

AU - Tada, Tomofumi

AU - Osuga, Takafumi

AU - Murase, Takashi

AU - Fujita, Makoto

AU - Nishino, Tomoaki

AU - Kiguchi, Manabu

AU - Fujii, Shintaro

PY - 2018

Y1 - 2018

N2 - Here, we report a facile procedure based on surface self-assembly for controlling the π-π stacking order and relevant rectified charge transport properties in stacks of aromatic molecules on a single-molecule scale. A high rectification ratio of 10 was achieved and the rectification direction was uniquely determined by the controlled stacking order of the aromatic molecules on the graphene layers of HOPG.

AB - Here, we report a facile procedure based on surface self-assembly for controlling the π-π stacking order and relevant rectified charge transport properties in stacks of aromatic molecules on a single-molecule scale. A high rectification ratio of 10 was achieved and the rectification direction was uniquely determined by the controlled stacking order of the aromatic molecules on the graphene layers of HOPG.

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DO - 10.1039/c8cc06430j

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JO - Chemical Communications

JF - Chemical Communications

IS - 88

ER -

Controlling stacking order and charge transport in π-stacks of aromatic molecules based on surface assembly

Abstract

All Science Journal Classification (ASJC) codes

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