Controlling the incorporation and release of C60 in nanometer-scale hollow spaces inside single-wall carbon nanohorns

Ryota Yuge, Masako Yudasaka, Jin Miyawaki, Yoshimi Kubo, Toshinari Ichihashi, Hideto Imai, Eiichi Nakamura, Hiroyuki Isobe, Hideki Yorimitsu, Sumio Iijima

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38 Citations (Scopus)

Abstract

We succeeded in large-scale preparation of single-wall carbon nanohorns (SWNH) encapsulating C60 molecules in a liquid phase at room temperature using a "nano-precipitation" method, that is, complete evaporation of the toluene from a C60-SWNH-toluene mixture. The C60 molecules were found to occupy 6-36% of the hollow space inside the SWNH, depending on the initial quantity of C60. We showed that the C60 in C60@SWNHox was quickly released in toluene, and the release rate decreased by adding ethanol to toluene. Numerical analysis of the release profiles indicated that there were fast and slow release processes. We consider that the incorporation quantity and the release rate of C 60 were controllable in/from SWNHs because SWNHs have large diameters, 2-5 nm.

Original languageEnglish
Pages (from-to)17861-17867
Number of pages7
JournalJournal of Physical Chemistry B
Volume109
Issue number38
DOIs
Publication statusPublished - Sep 29 2005
Externally publishedYes

All Science Journal Classification (ASJC) codes

  • Physical and Theoretical Chemistry
  • Surfaces, Coatings and Films
  • Materials Chemistry

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    Yuge, R., Yudasaka, M., Miyawaki, J., Kubo, Y., Ichihashi, T., Imai, H., Nakamura, E., Isobe, H., Yorimitsu, H., & Iijima, S. (2005). Controlling the incorporation and release of C60 in nanometer-scale hollow spaces inside single-wall carbon nanohorns. Journal of Physical Chemistry B, 109(38), 17861-17867. https://doi.org/10.1021/jp052814d