TY - JOUR
T1 - Coordination pillared layers using a dinuclear Mn(V) complex as a secondary building unit
AU - Ohtani, Ryo
AU - Kitagawa, Susumu
AU - Ohba, Masaaki
N1 - Funding Information:
This work was supported by a Grant-in-Aid for Science Research in a Priority Area ‘Coordination Programming (No. 24108102 )’ and a Grant-in-Aid for Scientific Research Program (No. 23245014 ) from the Ministry of Education, Culture, Sports, Science and Technology of Japan . R.O. is grateful to JSPS Research Fellowships for Young Scientists.
PY - 2013/3/22
Y1 - 2013/3/22
N2 - Coordination pillared layers (CPLs) are among the most attractive framework compounds displaying unique porous properties depending on their components. Three-dimensional Hofmann-type porous coordination polymers consisting of pillared cyanide-bridged layers with a tetracyanometallate anion [M II(CN)4]2- (M = Ni, Pd, Pt) as a secondary building unit (SBU) are the representative functional CPLs. In this paper, we report a new synthetic strategy for constructing CPLs using a new SBU linking two tetracyanometallate complexes, [{MnV(N)(CN)4} 2(bpy)]4- (bpy = 4,4′-bipyridyl). The [Mn V(N)(CN)4]2- part in the SBU permits expansion of the 2-D cyanide-bridged layers and the pillar part bpy simultaneously links the layers. Two CPLs, [MII(bpy){MnV(N)(CN) 4(bpy)1/2}]·MeCN·H2O (M = Zn, Cd), were synthesized by applying the SBU and characterized by X-ray single-crystal structural analysis and gas adsorption measurements.
AB - Coordination pillared layers (CPLs) are among the most attractive framework compounds displaying unique porous properties depending on their components. Three-dimensional Hofmann-type porous coordination polymers consisting of pillared cyanide-bridged layers with a tetracyanometallate anion [M II(CN)4]2- (M = Ni, Pd, Pt) as a secondary building unit (SBU) are the representative functional CPLs. In this paper, we report a new synthetic strategy for constructing CPLs using a new SBU linking two tetracyanometallate complexes, [{MnV(N)(CN)4} 2(bpy)]4- (bpy = 4,4′-bipyridyl). The [Mn V(N)(CN)4]2- part in the SBU permits expansion of the 2-D cyanide-bridged layers and the pillar part bpy simultaneously links the layers. Two CPLs, [MII(bpy){MnV(N)(CN) 4(bpy)1/2}]·MeCN·H2O (M = Zn, Cd), were synthesized by applying the SBU and characterized by X-ray single-crystal structural analysis and gas adsorption measurements.
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U2 - 10.1016/j.poly.2012.08.006
DO - 10.1016/j.poly.2012.08.006
M3 - Article
AN - SCOPUS:84875433553
SN - 0277-5387
VL - 52
SP - 591
EP - 597
JO - Polyhedron
JF - Polyhedron
ER -