TY - JOUR
T1 - Copper-catalyzed oxidative cleavage of carbon-carbon double bond of enol ethers with molecular oxygen
AU - Tokunaga, Makoto
AU - Shirogane, Yuki
AU - Aoyama, Hiroshi
AU - Obora, Yasushi
AU - Tsuji, Yasushi
N1 - Funding Information:
This work was supported by Grant-in-Aid for Scientific Research on Priority Areas (No. 16033204, Reaction Control of Dynamic Complexes) from Ministry of Education, Culture, Sports, Science and Technology, Japan.
PY - 2005/11/15
Y1 - 2005/11/15
N2 - A novel CC bond cleavage reaction of aromatic enol ethers (1) to give ketones (2) using molecular oxygen as oxidant is described. Among the examined catalysts (Cu(II), Pd(II), Ru(II), and H+), CuCl2 exhibited the highest activity. The reaction proceeded smoothly with several kinds of substrates.
AB - A novel CC bond cleavage reaction of aromatic enol ethers (1) to give ketones (2) using molecular oxygen as oxidant is described. Among the examined catalysts (Cu(II), Pd(II), Ru(II), and H+), CuCl2 exhibited the highest activity. The reaction proceeded smoothly with several kinds of substrates.
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U2 - 10.1016/j.jorganchem.2005.05.018
DO - 10.1016/j.jorganchem.2005.05.018
M3 - Article
AN - SCOPUS:27644503604
SN - 0022-328X
VL - 690
SP - 5378
EP - 5382
JO - Journal of Organometallic Chemistry
JF - Journal of Organometallic Chemistry
IS - 23
ER -