Abstract
To establish a new methodology for superheavy element chemistry, the coprecipitation behaviors of 34 elements with samarium hydroxide were investigated using multitracer produced by a spallation of Ta. The chemical reactions were rapidly equilibrated within 10 s for many elements. In addition, these elements exhibited individual coprecipitation behaviors, and the behaviors were qualitatively related to their hydroxide precipitation behaviors. It was demonstrated that the ammine and hydroxide complex formations of superheavy elements could be investigated using the established method.
| Original language | English |
|---|---|
| Pages (from-to) | 105-116 |
| Number of pages | 12 |
| Journal | Applied Radiation and Isotopes |
| Volume | 118 |
| DOIs | |
| Publication status | Published - Dec 1 2016 |
| Externally published | Yes |
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All Science Journal Classification (ASJC) codes
- Radiation
Cite this
Coprecipitation experiment with Sm hydroxide using a multitracer produced by nuclear spallation reaction : A tool for chemical studies with superheavy elements. / Kasamatsu, Yoshitaka; Yokokita, Takuya; Toyomura, Keigo; Shigekawa, Yudai; Haba, Hiromitsu; Kanaya, Jumpei; Huang, Minghui; Ezaki, Yutaka; Yoshimura, Takashi; Morita, Kosuke; Shinohara, Atsushi.
In: Applied Radiation and Isotopes, Vol. 118, 01.12.2016, p. 105-116.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Coprecipitation experiment with Sm hydroxide using a multitracer produced by nuclear spallation reaction
T2 - A tool for chemical studies with superheavy elements
AU - Kasamatsu, Yoshitaka
AU - Yokokita, Takuya
AU - Toyomura, Keigo
AU - Shigekawa, Yudai
AU - Haba, Hiromitsu
AU - Kanaya, Jumpei
AU - Huang, Minghui
AU - Ezaki, Yutaka
AU - Yoshimura, Takashi
AU - Morita, Kosuke
AU - Shinohara, Atsushi
PY - 2016/12/1
Y1 - 2016/12/1
N2 - To establish a new methodology for superheavy element chemistry, the coprecipitation behaviors of 34 elements with samarium hydroxide were investigated using multitracer produced by a spallation of Ta. The chemical reactions were rapidly equilibrated within 10 s for many elements. In addition, these elements exhibited individual coprecipitation behaviors, and the behaviors were qualitatively related to their hydroxide precipitation behaviors. It was demonstrated that the ammine and hydroxide complex formations of superheavy elements could be investigated using the established method.
AB - To establish a new methodology for superheavy element chemistry, the coprecipitation behaviors of 34 elements with samarium hydroxide were investigated using multitracer produced by a spallation of Ta. The chemical reactions were rapidly equilibrated within 10 s for many elements. In addition, these elements exhibited individual coprecipitation behaviors, and the behaviors were qualitatively related to their hydroxide precipitation behaviors. It was demonstrated that the ammine and hydroxide complex formations of superheavy elements could be investigated using the established method.
UR - http://www.scopus.com/inward/record.url?scp=84986587244&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=84986587244&partnerID=8YFLogxK
U2 - 10.1016/j.apradiso.2016.09.003
DO - 10.1016/j.apradiso.2016.09.003
M3 - Article
AN - SCOPUS:84986587244
VL - 118
SP - 105
EP - 116
JO - Applied Radiation and Isotopes
JF - Applied Radiation and Isotopes
SN - 0969-8043
ER -