Coprecipitation experiment with Sm hydroxide using a multitracer produced by nuclear spallation reaction: A tool for chemical studies with superheavy elements

Yoshitaka Kasamatsu, Takuya Yokokita, Keigo Toyomura, Yudai Shigekawa, Hiromitsu Haba, Jumpei Kanaya, Minghui Huang, Yutaka Ezaki, Takashi Yoshimura, Kosuke Morita, Atsushi Shinohara

Research output: Contribution to journalArticle

1 Citation (Scopus)

Abstract

To establish a new methodology for superheavy element chemistry, the coprecipitation behaviors of 34 elements with samarium hydroxide were investigated using multitracer produced by a spallation of Ta. The chemical reactions were rapidly equilibrated within 10 s for many elements. In addition, these elements exhibited individual coprecipitation behaviors, and the behaviors were qualitatively related to their hydroxide precipitation behaviors. It was demonstrated that the ammine and hydroxide complex formations of superheavy elements could be investigated using the established method.

Original languageEnglish
Pages (from-to)105-116
Number of pages12
JournalApplied Radiation and Isotopes
Volume118
DOIs
Publication statusPublished - Dec 1 2016
Externally publishedYes

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spallation
hydroxides
ammines
samarium
chemical reactions
methodology
chemistry

All Science Journal Classification (ASJC) codes

  • Radiation

Cite this

Coprecipitation experiment with Sm hydroxide using a multitracer produced by nuclear spallation reaction : A tool for chemical studies with superheavy elements. / Kasamatsu, Yoshitaka; Yokokita, Takuya; Toyomura, Keigo; Shigekawa, Yudai; Haba, Hiromitsu; Kanaya, Jumpei; Huang, Minghui; Ezaki, Yutaka; Yoshimura, Takashi; Morita, Kosuke; Shinohara, Atsushi.

In: Applied Radiation and Isotopes, Vol. 118, 01.12.2016, p. 105-116.

Research output: Contribution to journalArticle

Kasamatsu, Yoshitaka ; Yokokita, Takuya ; Toyomura, Keigo ; Shigekawa, Yudai ; Haba, Hiromitsu ; Kanaya, Jumpei ; Huang, Minghui ; Ezaki, Yutaka ; Yoshimura, Takashi ; Morita, Kosuke ; Shinohara, Atsushi. / Coprecipitation experiment with Sm hydroxide using a multitracer produced by nuclear spallation reaction : A tool for chemical studies with superheavy elements. In: Applied Radiation and Isotopes. 2016 ; Vol. 118. pp. 105-116.
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